Product: MIL-101(Cr)
Synonyms: NA
CAS：869288-09-5
Basic Information
| Unit MF. | C24H12O15FCr3 | Unit MW. | 715.33 | ||
| Coordination Metal | Cr | Linkers | Terephthalic acid (CAS:100-21-0） | ||
| Aperture |
Aperture:1.2-1.6nm; Pore Size: 2.9-3.4nm |
Pore volume | 2.0-2.4 cm3/g | ||
| Surface Area | BET Specific surface 2800-3200 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Grey Green Powder |  |
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| Particle Size |
500nm-1um |
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Stability
1) MIL-101(Cr) is stable in air and acqeous solutions (PH 1-12)
2）Thermal stability, thermal decomposition temperature above 300 ° C
2）Thermal stability, thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 10 hours at 110 degree in vacuum before gas-adsorption test.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
Characterizations
References
1) G. Férey, C. Mellot-Draznieks, C. Serre, F. Millange, J. Dutour, S. Surblé, I. Margiolaki, Science 2005, 309(5743), 2040-2042, DOI: 10.1126/science.1116275 ; A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area;
2）Lomig Hamon, Christian Serre, Thomas Devic, Thierry Loiseau, Franck Millange, Gérard Férey, Guy De Weireld; Journal of the American Chemical Society, 2009, 131, 25; DOI：10.1021/ja901587t; Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal-Organic Frameworks at Room Temperature.；
3）Young Kyu Hwang, Do-Young Hong, Jong-San Chang, Sung Hwa Jhung, You-Kyong Seo, Jinheung Kim, Alexandre Vimont, Marco Daturi, Christian Serre, Gerard Ferey; Angewandte Chemie International Edition, 2008, 47, 4144-4148; DOI：10.1002/anie.200705998; Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation；
4）Philip L. Llewellyn, Sandrine Bourrelly, Christian Serre, Alexandre Vimont, Marco Daturi, Lomig Hamon, Guy De Weireld, Jong-San Chang, Do-Young Hong, Young Kyu Hwang, Sung Hwa Jhung, Gérard Ferey; Langmuir, 2008, 24, 14, 7245-7250; DOI：10.1021/la800227x; High Uptakes of CO₂ and CH₄ in Mesoporous Metal-Organic Frameworks MIL-100 and MIL-101；
5）Sara Sorribas, Patricia Gorgojo, Carlos Tellez, Joaquín Coronas, Andrew G. Livingston; Journal of the American Chemical Society, 2013, 135, 15201-15208; DOI：10.1021/ja407665w; High Flux Thin Film Nanocomposite Membranes Based on Metal−Organic Frameworks for Organic Solvent Nanofiltration；
6）Enamul Haque, Ji Eun Lee, In Tae Jang, Young Kyu Hwang, Jong-San Chang, Jonggeon Jegal, Sung Hwa Jhung; Journal of Hazardous Materials, 2010, 181, 535-542; DOI：10.1016/j.jhazmat.2010.05.047; Adsorptive removal of methyl orange from aqueous solution with metal-organic frameworks, porous chromium-benzenedicarboxylates；
7）Sung Hwa Jhung, Jin-Ho Lee, Ji Woong Yoon, Christian Serre, Gérard Férey, Jong-San Chang*; Advanced Materials, 2007, 19, 121-124; DOI：10.1002/adma.200601604; Microwave Synthesis of Chromium Terephthalate MIL‐101 and Its Benzene Sorption Ability；
8）Lomig Hamon, Christian Serre, Thomas Devic, Thierry Loiseau, Franck Millange, Gérard Férey, Guy De Weireld；Journal of the American Chemical Society, 2009, Volume 131, Issue 25；DOI：10.1021/ja901587t；Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal-Organic Frameworks at Room Temperature；
9）Cheng-Xiong Yang and Xiu-Ping Yan*;Analytical Chemistry, 2011, 83, 7144–7150; DOI：10.1021/ac201517c; Metal-Organic Framework MIL-101(Cr) for High-Performance Liquid Chromatographic Separation of Substituted Aromatics
