Product: SIFSIX-2-Cu-i
Synonyms: [Cu(dpa)2SiF6-i]
CAS:NA
Basic Information
Unit MF. | C24H8N4F6SiCu | Unit MW. | 557.97 | ||
Coordination Metal | Cu | Linkers |
1,2-bis(4-pyridyl)ethyne (CAS:73564-69-9) |
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Pore Size | 0.5nm | Pore volume | 0.2 cm3/g | ||
Surface Area | NA | ||||
Analog Structure | ![]() ![]() |
Product Property
Appearance | Grey Purple Powders | |||
Particle Size | irregular bulk particles |
Stability
1) SIFSIX-2-Cu-i is stable in air and aqueous solution for weeks
2) Thermal decomposition temperature above 300 ° C
2) Thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate 12 hours at room temperature in vacuum
Other Features
Fluorescence:NA
Applications
1) Gas adsorption (e.g. CO2, SO2)
2) Gas Separation (ethane/ethylene)
2) Gas Separation (ethane/ethylene)
Characterizations
References
1) Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.; Cairns, Amy J.; Luebke, Ryan; Forrest, Katherine; Pham, Tony; Ma, Shengqian; Space, Brian; Wojtas, Lukasz; Eddaoudi, Mohamed; Zaworotko, Michael J.; Nature 2013), 495(7439), 80-84, DOI: 10.1038/nature11893 ; Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
2) Qian, Siheng; Xia, Ling; Yang, Lifeng; Wang, Xiaobing; Suo, Xian; Cui, Xili; Xing, Huabin From Journal of Membrane Science (2020)611, 118329, DOI: 10.1016/j.memsci.2020.118329 ; Defect-free mixed-matrix membranes consisting of anion-pillared metal-organic frameworks and poly(ionic liquid)s for separation of acetylene from ethylene