Product: [Zn(ZnOH)₄(bibta)₃]
Synonyms: NCFA-1
CAS：2247121-93-1
Basic Information
| Unit MF. | C36H22N18O4Zn5 | Unit MW. | 1097.66 | ||
| Coordination Metal | Zn | Linkers | 5,5′-bibenzotriazolate（H2bibta）CAS: 15805-13-7 | ||
| Pore Size | NA | Pore volume | NA | ||
| Surface Area | BET> 2000 m²/g | ||||
| Analog Structure | NA | ||||
Product Property
| Appearance | Off-white solid | |||
| Particle Size | NA | |||
Stability
1) Good stability in solution and humid conditions
2) Thermal stability: thermal decomposition temperature around 400℃
Preservation
1) Keep in dry and cool condition
2) Activate by heating at 100℃ under vacuum.
Other Features
Fluorescence: NA
Applications
1) To be used for trace CO₂ capture from the air and other gas mixtures, such as the internal environment of submarines and spacecraft.
Characterizations
References
1) Caitlin E. Bien, Kai K. Chen, Szu - Chia Chien, Benjamin R. Reiner, Li - Chiang Lin, Casey R. Wade, W. S. Winston Ho; J. Am. Chem. Soc. 2018, 140, 12662−12666, DOI: 10.1021/jacs.8b06109, Bioinspired Metal−Organic Framework for Trace CO₂ Capture；
2）Weigang Zheng, Zhihong Tian, Zhen Wang, Donglai Peng, Yongsheng Zhang, Jing Wang, Yatao Zhang；Separation and Purification Technology, 2021；DOI：10.1016/j.seppur.2021.120371；Dual-function biomimetic carrier based facilitated transport mixed matrix membranes with high stability for efficient CO₂/N₂ separation；
3）Caitlin E. Bien, Zhongzheng Cai, Casey R. Wade;Inorganic Chemistry, 2021, 60, 11784-11794; DOI：10.1021/acs.inorgchem.1c01077; Using Postsynthetic X-Type Ligand Exchange to Enhance CO₂ Adsorption in Metal-Organic Frameworks with Kuratowski-Type Building Units；
4）Denghui Ma, Zexing Cao; The Journal of Physical Chemistry C, 2022, 126, 19159−19168; DOI：10.1021/acs.jpcc.2c05943; Adsorption and Degradation of the G‑Type Nerve Agent Soman and Its Simulant Dimethyl 4‑Nitrophenylphosphate by Metal-Exchange-Modified MFU‑4l Metal−Organic Frameworks；
