Product: SIFSIX-3-Ni
Synonyms: [Ni(pz)2(SiF6)]
CAS：1801992-25-5
Basic Information
| Unit MF. | C8H8F6N4NiSi | Unit MW. | 360.95 | ||
| Coordination Metal | Ni | Linker |
Pyrazine (pz) |
||
| Pore Size | / | Pore Volume | / | ||
| Surface Area | 368 m²/g | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | Blue powder | |||
| Particle Size | / | |||
Stability
1) Stable in water, ethanol, and other common solvents
2) Thermal stability up to 300°C
2) Thermal stability up to 300°C
Preservation
1) Store in a dry and cool place
2) Activate by heating at room temperature in a vacuum oven for 3 hours
Other Features
Fluorescence: NA
Applications
1) Efficient CO2 capture from flue gas
2) Selective adsorption of CO2 over N2 and water vapor
3) Potential for industrial gas separation applications
2) Selective adsorption of CO2 over N2 and water vapor
3) Potential for industrial gas separation applications
Characterizations
References
1) Elsaidi, Sameh K.; Mohamed, Mona H.; Schaef, Herbert T.; Kumar, Amrit; Lusi, Matteo; Pham, Tony; Forrest, Katherine A.; Space, Brian; Xu, Wenqian; Halder, Gregory J.; Liu, Jun; Zaworotko, Michael J.; Thallapally, Praveen K.; Chem. Commun., 2015, 51, 15530–15533, DOI: 10.1039/c5cc06577a; Hydrophobic pillared square grids for selective removal of CO2 from simulated flue gas;
2) Yang, L. F., Cui, X. L., Yang, Q. W., Qian, S. H., Wu, H., Bao, Z. B., Zhang, Z. G., Ren, Q. L., Zhou, W., Chen, B., Xing, H. B. (2018). Advanced Materials, 30(1), 1705374. DOI: 10.1002/adma.201705374; A Single-Molecule Propyne Trap: Highly Efficient Removal of Propyne from Propylene with Anion-Pillared Ultramicroporous Materials;
3）Jieyi Zheng, Xili Cui, Qiwei Yang, Qilong Ren, Yiwen Yang, Huabin Xing; Chemical Engineering Journal, 2018, 354, 1075-1082; DOI：10.1016/j.cej.2018.08.119; Shaping of ultrahigh-loading MOF pellet with a strongly anti-tearing binder for gas separation and storage;
4) Daniel O’Nolan, Amrit Kumar, Michael J. Zaworotko*; Journal of the American Chemical Society, 2017, 139, 8508-8513; DOI：10.1021/jacs.7b01682; Water Vapor Sorption in Hybrid Pillared Square Grid Materials;
5) Sameh K. Elsaidi, Mona H. Mohamed, Herbert T. Schaef, Amrit Kumar, Matteo Lusi, Tony Pham, Katherine A. Forrest, Brian Space, Wenqian Xu, Gregory J. Halder, Jun Liu, Michael J. Zaworotko, Praveen K. Thallapally; Chem. Commun., 2015, 51, 15530-15533; DOI ：10.1039/c5cc06577a; Hydrophobic pillared square grids for selective removal of CO₂ from simulated flue gas;
6) Valeriya Chernikova, Osama Shekhah, Youssef Belmabkhout, Mohamed Eddaoudi*; ACS Applied Nano Materials, 2020, 3, 6432-6439; DOI：10.1021/acsanm.0c00909; Nanoporous Fluorinated Metal-Organic Framework-Based Membranes for CO₂ Capture;
7) Katherine A. Forrest, Tony Pham, Sameh K. Elsaidi, Mona H. Mohamed, Praveen K. Thallapally, Michael J. Zaworotko, Brian Space; Crystal Growth & Design, 2019, 19, 3732-3743; DOI：10.1021/acs.cgd.9b00086; Investigating CO₂ Sorption in SIFSIX-3-M (M = Fe, Co, Ni, Cu, Zn) through Computational Studies
