Product: [Cu4I4(DABCO)2]
Synonyms: (CuI)4(DABCO)2；Bis(1,4-diazabicyclo[2.2.2]octane)tetra(copper(I) iodide)
CAS: 928170-42-7
Basic Information
| Unit MF. | C12H24Cu4I4N4 | Unit MW. | 986.11 | ||
| Coordination Metal | Cu | Linkers |
1,4-Diazabicyclo[2.2.2]octane (DABCO) |
||
| Pore Size | ~7.06 Å | Pore Volume | 20.5% per unit cell | ||
| Surface Area | Not specified | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | White powder | |||
| Particle Size | ||||
Stability
1) Thermal stability: Decomposes above 200°C
Preservation
1) Keep in dry and cool conditions
2) Degassing the sample by heating at room temperature for 3 hours
Other Features
Luminescence: Yes, emission maxima at 556 nm (II) and 580 nm (I) at room temperature
Applications
1) Potential for gas storage due to high porosity and large open channels
2) Luminescent materials due to strong luminescence properties
Characterizations
References
1) Dario Braga, Lucia Maini, Paolo P. Mazzeo, Barbara Ventura; Chem. Eur. J. 2010, 16, 1553–1559; DOI: 10.1002/chem.200900743; Reversible Interconversion between Luminescent Isomeric Metal–Organic Frameworks of [Cu4I4(DABCO)2]；
2) Yao Kang, Fei Wang, Jian Zhang, Xianhui Bu; Journal of the American Chemical Society, 2012, 134, 17881−17884; DOI：10.1021/ja308801n; Luminescent MTN-Type Cluster−Organic Framework with 2.6 nm Cages；
3）Minghui Bi, Guanghua Li, Jia Hua, Xiaomin Liu, Yawei Hu, Zhan Shi, Shouhua Feng; CrystEngComm, 2007, 9, 984-986; DOI：10.1039/b709852a; A coordination polymer of copper(I) iodide with 6⁵4 topology constructed from Cu₄I₄(DABCO)₄；
