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MIL-125-Ti

MIL-125-Ti

CAS NO.:1193372-03-0Formula:C48H28O36Ti8Weight: 1563.65

Product: MIL-125Ti
Synonyms: NA
CAS:1193372-03-0

Basic Information
Unit MF. C48H4O36Ti8 Unit MW. 1539.46
Coordination  Metal Ti Linkers

Terephthalic acid(CAS:100-21-0)

Pore Size 0.6nm; 1.25nm Pore volume  0.65g/cm3
Surface Area BET  1300 m2/g 
Analog Structure   
Product Property
Appearance Off-white Powder  
Particle Size 500nm-5um irregular particles
Stability
1) MIL-125(Ti) could be stable for days when kept dry and sealed. It is instable in solution and moisture.
2) Thermal decomposition temperature higher than 350 ° C
Preservation
1) Keep sealed in dry and cool condition 
2) It is recommended to activate for 3 hours at 150 degree in vacuum
Other Features
Fluorescence:NA
Applications
1) Gas and pollute adsorption
2) MIL-125(Ti) is of photocatalytical activity
Characterizations
XRD
SEM
BET
NA
FTIR
NA
References
1) M. Dan-Hardi, C. Serre, T. Frot, L. Rozes, G. Maurin, C. Sanchez, G Férey, J. Am. Chem. Soc. 2009, 10857-10859, DOI: 10.1021/ja903726m ; A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate;
2)Hou Wang, Xingzhong Yuan, Yan Wu, Guangming Zeng, Xiaohong Chen, Lijian Leng, Zhibin Wu, Longbo Jiang, Hui Li;Journal of Hazardous Materials, 2015, 286, 187-194; DOI:10.1016/j.jhazmat.2014.11.039; Facile synthesis of amino-functionalized titanium metal−organic frameworks and their superior visible-light photocatalytic activity for Cr(VI) reduction;
3) Frederik Vermoortele, Michael Maes, Peyman Z. Moghadam, Matthew J. Lennox, Florence Ragon, Mohammed Boulhout, Shyam Biswas, Katrien G. M. Laurier, Isabelle Beurroies, Renaud Denoyel, Maarten Roeffaers, Norbert Stock, Tina Düren, Christian Serre, Dirk E. De Vos*;Journal of the American Chemical Society, 2011, 133, 18526-18529; DOI:10.1021/ja207287h; p-Xylene-Selective Metal–Organic Frameworks: A Case of Topology-Directed Selectivity;