Product: [Co(5-NH2-bdc)(bpy)]
Synonyms: Co(AIP)(BPY)
CAS：1177410-74-0
Basic Information
| Unit MF. | C26H20N4O10Co2.H2O | Unit MW. | 684.34 | ||
| Coordination Metal | Co | Linkers | 5-aminoisophthalic acid（CAS：99-31-0） Bipyridine（CAS： 553-26-4） | ||
| Pore Size |
8A |
Pore volume | / | ||
| Surface Area | no N2 Adsorption | ||||
| Analog Structure | |||||
Product Property
| Appearance | Purple Crystals |  |
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Stability
1) [Co(5-NH2-bdc)(bpy)] is stable in air and neutral solutions
2) High thermal stability, thermal decomposition temperature about 350 ° C
2) High thermal stability, thermal decomposition temperature about 350 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 10 hours at 120 degree in vacuum before gas adsorption test.
2) It is recommended to activate for 10 hours at 120 degree in vacuum before gas adsorption test.
Other Features
Fluorescence:NA
Applications
1) [Co(5-NH2-bdc)(bpy)] is prospective in separation of C3H8/C3H6
Characterizations
References
1) Hu Y, Zhang W, Zhang X, Wang Z, Li Y, Bai J. Inorg Chem Commun. 2009,12(2),166-168, DOI: 10.1016/j.inoche.2008.12.005 ; Two corrugated 2D bilayer (63)(658) topological coordination polymers: synthesis, structure, and water-induced reversible transformation.
2) M. Zeng, S. Hu, Q. Chen, G. Xie, Q. Shuai, S. Gao, L.Y. Tang, Inorg. Chem. 2009, 48, 7070–7079, DOI: 10.1021/ic801794e ; Apical Ligand Substitution, Shape Recognition, Vapor-Adsorption Phenomenon, and Microcalorimetry for a Pillared Bilayer Porous Framework That Shrinks or Expands in Crystal-to-Crystal Manners upon Change in the Cobalt(II) Coordination Environment
3) H. Wu, Y. Yuan, Y. Chen, F. Xu, D. Lv, Y. Wu, Z. Li, Q. Xia, AIChE J. 2020, 66:e16858, DOI: 10.1002/aic.16858 ; Efficient adsorptive separation of propene over propane through a pillar-layer cobalt-based metal–organic framework
