Product Name:1,4-Di((3,5-dicarboxyphenyl)ethynyl)benzene
Synonymous:TCB ; H4TCB ; PDEB;5,5'-(1,4-Phenylenedi-2,1-ethynediyl)bis[1,3-benzenedicarboxylic acid]
CAS:957014-40-3
3) Zhao, Jian-Feng; Li, Yi-Bao; Lin, Zong-Qiong; Xie, Ling-Hai; Shi, Nai-En; Wu, Xing-Kui; Wang, Chen; Huang, Wei; J. Phys. Chem. C 2010, 114(21), 9931-9937, DOI: 10.1021/jp1022482 ; Molecule Length Directed Self-Assembly Behavior of Tetratopic Oligomeric Phenylene-Ethynylenes End-Capped with Carboxylic Groups by Scanning Tunneling Microscopy
4) Zheng, Baishu; Yun, Ruirui; Bai, Junfeng; Lu, Zhiyong; Du, Liting; Li, Yizhi; Inorg. Chem. 2013, 52(6), 2823-2829, DOI :10.1021/ic301598n ; Expanded Porous MOF-505 Analogue Exhibiting Large Hydrogen Storage Capacity and Selective Carbon Dioxide Adsorption
Synonymous:TCB ; H4TCB ; PDEB;5,5'-(1,4-Phenylenedi-2,1-ethynediyl)bis[1,3-benzenedicarboxylic acid]
CAS:957014-40-3
Basic Info
M.F. | C26H14O8 | M.W. | 454.38456 | ||
Appearance |
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:NJU-Bai12 [r4]; UHM-8 , UHM-9 [r5]
Characterization
Reference
1) Daniell, Heather W.; Klotz, Eric J. F.; Odell, Barbara; Claridge, Tim D. W.; Anderson, Harry L.; Angew. Chem., Int. Ed. 2007, 46(36), 6845-6848, DOI: 10.1002/anie.200702349 ; Solid-phase synthesis of oligo(phenylene ethynylene) rotaxanes
2) Zhou, Hui; Dang, Hung; Yi, Ji-Hyun; Nanci, Antonio; Rochefort, Alain; Wuest, James D.; Journal of the American Chemical Society 2007, 129(45), 13774-13775, DOI: 10.1021/ja0742535 ; Frustrated 2D Molecular Crystallization5) Frahm, Daniela; Hoffmann, Frank; Froeba, Michael; Cryst. Growth & Des. 2014, 14(4), 1719-1725, DOI: 10.1021/cg4018536 ; Two Metal-Organic Frameworks with a Tetratopic Linker: Solvent-Dependent Polymorphism and Postsynthetic Bromination