Product: MOF-74(Co)
Synonyms: Co-MOF-74 ; Co-DOBDC; CPO-27(Co); Co2(dhtp)
CAS：871658-67-2
Basic Information
| Unit MF. | C8H4O8Co2 | Unit MW. | 345.97896 | ||
| Coordination Metal | Co | Linkers | 2,5-Dihydroxyterephthalic acid (CAS: 610-92-4) | ||
| Aperture |
1.2 nm |
Pore volume | 0.6 cm3/g | ||
| Surface Area | BET Specific surface 1100 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Brick-Red Powder |  |
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| Particle Size | 3-5um irregular bulk particles | |||
Stability
1) MOF-74(Co) is stable in air for weeks, but decomposed gradually in wet and hot conditions. It is instable in acqueous solutions.
2）Thermal stability, thermal decomposition temperature above 250 ° C
2）Thermal stability, thermal decomposition temperature above 250 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for >6 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (e.g. carbon dioxide & CH4) and pollutant air adsorption
2) MOF-74 is instable in acqueous solutions, thus it could be used for drug adsorption and release
2) MOF-74 is instable in acqueous solutions, thus it could be used for drug adsorption and release
Characterizations
References
1）J.K. Nathaniel, L. Rosi, Eddaoudi Mohamed, Banglin Chen, Michael O'Keeffe, Omar M. Yaghi, J. Am. Chem. Soc. 2005, 127, 1504–1518, DOI: 10.1021/ja045123o ; Rod packings and Metal−Organic frameworks constructed from rod-shaped secondary building units；
2） Sun, Dengrong; Sun, Fangxiang; Deng, Xiaoyu; Li, Zhaohui; Inorg. Chem. 2015, 54(17), 8639-8643, DOI: 10.1021/acs.inorgchem.5b01278 ; Mixed-Metal Strategy on Metal-Organic Frameworks (MOFs) for Functionalities Expansion: Co Substitution Induces Aerobic Oxidation of Cyclohexene over Inactive Ni-MOF-74；
3) Matthew T. Kapelewski, Tomče Runčevski, Jacob D. Tarver, Henry Z. H. Jiang, Katherine E. Hurst, Philip A. Parilla, Anthony Ayala, Thomas Gennett, Stephen A. FitzGerald, Craig M. Brown, Jeffrey R. Long*; Chemistry of Materials, 2018, 30, 8179-8189; DOI：10.1021/acs.chemmater.8b03276; Record High Hydrogen Storage Capacity in the Metal-Organic Framework Ni₂(m-dobdc) at Near-Ambient Temperatures
