Product Name：Tris(benzimidazolylmethyl)amine
Synonymous：(BimH)3 ; TBIA ; 3-TPyMNTB;1-(1H-Benzimidazol-2-yl)-N,N-bis(1H-benzimidazol-2-ylmethyl)methanamine; N,N,N-Tris(1H-benzimidazol-2-ylmethyl)amine; N,N,N-Tris(2-benzimidazolylmethyl)amine; TCMDC 124132; Tris(1H-benzimidazol-2-ylmethyl)amine; Tris(2-benzimidazolylmethyl)amine; Tris(2-benzimidazoylmethyl)amine; Tris(benzimidazole-2-yl-methyl)amine;
CAS：64019-57-4
3) Tang, Yongming; Zhang, Fan; Hu, Shengxiang; Cao, Ziyi; Wu, Zhenglei; Jing, Wenheng; Corrosion Science 2013, 74, 271-282, DOI: 10.1016/j.corsci.2013.04.053 ; Novel benzimidazole derivatives as corrosion inhibitors of mild steel in the acidic media. Part I: Gravimetric, electrochemical, SEM and XPS studies
4) Zhang, Shu-Ran; Du, Dong-Ying; Qin, Jun-Sheng; Bao, Shao-Juan; Li, Shun-Li; He, Wen-Wen; Lan, Ya-Qian; Shen, Ping; Su, Zhong-Min; Chem.- Eur. J. 2014, 20(13), 3589-3594, DOI: 10.1002/chem.201304692 ; A Fluorescent Sensor for Highly Selective Detection of Nitroaromatic Explosives Based on a 2D, Extremely Stable, Metal-Organic Framework
Synonymous：(BimH)3 ; TBIA ; 3-TPyMNTB;1-(1H-Benzimidazol-2-yl)-N,N-bis(1H-benzimidazol-2-ylmethyl)methanamine; N,N,N-Tris(1H-benzimidazol-2-ylmethyl)amine; N,N,N-Tris(2-benzimidazolylmethyl)amine; TCMDC 124132; Tris(1H-benzimidazol-2-ylmethyl)amine; Tris(2-benzimidazolylmethyl)amine; Tris(2-benzimidazoylmethyl)amine; Tris(benzimidazole-2-yl-methyl)amine;
CAS：64019-57-4
Basic Info
| M.F. | C24H21N7 | M.W. | 407.47044 | ||
| Appearance | |||||
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[Eu(3-TPyMNTB)2] [r5]; π-MnBr-cages [r6]
2) It is a catalyst for click reaction:[r2];
3) It can be used as correlation inhibitors:[r3];
Characterization
Reference
1) hompson, Laurence K.; Ramaswamy, Baratham S.; Seymour, Elizabeth A.; Canadian J. Chem. 1977, 55(5), 878-888, DOI: 10.1139/v77-122 ; Cobalt(II) and zinc(II) complexes of the 'tripod' ligand tris(2-benzimidazolylmethyl)amine. Some five-coordinate derivatives and some with mixed stereochemistries
2) Rodionov, Valentin O.; Presolski, Stanislav I.; Diaz Diaz, David; Fokin, Valery V.; Finn, M. G.; Journal of the American Chemical Society 2007, 129(42), 12705-12712, DOI: 10.1021/ja072679d ; Ligand-Accelerated Cu-Catalyzed Azide-Alkyne Cycloaddition: A Mechanistic Report5) iu, Yu; Pan, Mei; Yang, Qing-Yuan; Fu, Lei; Li, Kang; Wei, Shi-Chao; Su, Cheng-Yong; Chem. Mater. 2012, 24(10), 1954-1960, DOI: 10.1021/cm3008254 ; Dual-Emission from a Single-Phase Eu-Ag Metal-Organic Framework: An Alternative Way to Get White-Light Phosphor6) Li, Guo-Ling; Zhuo, Zhu; Wang, Bin; Cao, Xue-Li; Su, Hai-Feng; Wang, Wei; Huang, You-Gui; Hong, Maochun; Journal of the American Chemical Society 2021, 143(29), 10920-10929, DOI: 10.1021/jacs.1c01161 ; Constructing π-Stacked Supramolecular Cage Based Hierarchical Self-Assemblies via π···π Stacking and Hydrogen Bonding
