Product Name：4-[tris(4-formylphenyl)methyl]benzaldehyde
Synonymous：TFPM; 4,4',4'',4'''-methanetetrakis-benzaldehyde
CAS：617706-61-3
Synonymous：TFPM; 4,4',4'',4'''-methanetetrakis-benzaldehyde
CAS：617706-61-3
Basic Info
| M.F. | C29H20O4 | M.W. | 432.4667 | ||
| Appearance |  |
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Properties
1) 617706-61-3 Dissolved in DCM, DMF, DMSO, etc.
2) Sealed at 2-8 ℃
Appications
1) It could be used as monomer linker for COF synthesis：3D-COF [r2]; (benzimidazole-linked polymer) BILP-1 [r3]; (Porous imine-linked networks)PIN-2 [r4]; 3D-OH COF [r5]; 3D-IL-COFs [r6]
Characterization
Reference
1) Fournier, J.; Wang, X.; Wuest, J.; Canadian J. Chem. 2003, 81(5), 376-380, DOI:10.1139/V03-056 ; Derivatives of tetraphenylmethane and tetraphenylsilane: Synthesis of new tetrahedral building blocks for molecular construction
2) X. Guan, Y. Ma, H. Li, Y. Yusran, M. Xue, Q. Fang, Y. Yan, V. Valtchev, S. Qiu, J. Am. Chem. Soc. 2018, 140, 4494– 4498, DOI:10.1021/jacs.8b01320 ; Fast, Ambient Temperature and Pressure Ionothermal Synthesis of Three-Dimensional Covalent Organic Frameworks
3) Rabbani, M.; El-Kaderi, H.; Chem. Mater. 2011, 23(7), 1650-1653, DOI:10.1021/cm200411p
4) Popp, N.; Homburg, T.; Stock, N.; Senker, J.; J. Mater. Chem. A 2015, 3(36), 18492-18504, DOI:10.1039/C5TA02504D ; Porous imine-based networks with protonated imine linkages for carbon dioxide separation from mixtures with nitrogen and methane
5) Lu, Q.; Ma, Y.; Li, H.; Guan, X.; Yusran, Y.; Xue, M.; Fang, Q.; Yan, Y.; Qiu, S.; Valtchev, Valentin.; Angew. Chem., Int. Ed. 2018, 57(21), 6042-6048, DOI: 10.1002/anie.201712246
6) Guan, X.; Ma, Y.; Li, H.; Yusran, Y.; Xue, M.; Fang, Q.; Yan, Y.; Valtchev, V.; Qiu, S.; J. Am. Chem. Soc. 2018, 140, 13, 4494-4498, DOI: 10.1021/jacs.8b01320 ; Fast, Ambient Temperature and Pressure Ionothermal Synthesis of Three-Dimensional Covalent Organic Frameworks
