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Tris(4-aminophenyl)amine

Tris(4-aminophenyl)amine

CAS NO.:5981-09-9Formula:C18H18N4Weight: 290.36232
Product Name:tris(4-aminotriphenyl)amine
Synonymous:TAPA; bdta;  3PA; TPA; 1,​4-​Benzenediamine, N1,​N1-​bis(4-​aminophenyl)​-
CAS:5981-09-9
Basic Info
M.F.  C18H18N4 M.W.  290.36
Appearance  
Properties
1)  It is soluble in DCM, DMF, DMSO, etc.
2)  2-8 ℃ sealed storage
Appications
1) It could be used as monomer linker for COF synthesis:N-COF; TFPA-TAPA-COF;  PI-COF-1; 2TPA; BTMA-TAPA-COF [r1]; COF-77/78 [r3]
Characterization
HNMR
MS
FTIR
NA
HPLC
NA
Reference
1) L. Zhai, N. Huang, H. Xu, Q. Chen, D. Jiang, Chem. Commun. 2017, 53, 4242-4245, DOI:10.1039/C7CC01921A
2) L. Ascherl, T. Sick, J. T. Margraf, S. H. Lapidus, M. Calik, C. Hettstedt, K. Karaghiosoff, M. Döblinger, T. Clark, K. W. Chapman, F. Auras, T. Bein, Nat. Chem. 2016, 8, 310-316, DOI:10.1038/nchem.2444 
3) H. Nguyen,  C. Gropp,  O. Yaghi, J. Am. Chem. Soc. 2020, 142(6), 2771-2776, DOI:10.1021/jacs.9b13971
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