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hexa[4-(4-pyrindinyl)phenyl]benzene

hexa[4-(4-pyrindinyl)phenyl]benzene

CAS NO.:591215-23-5Formula:C72H48N6Weight: 997.19172
Product Name:hexa[4-(4’-pyrindinyl)phenyl]benzene
Synonymous:HPPB
CAS:591215-23-5
Basic Info
M.F.  C72H48N6 M.W.  997.19172
Appearance  
Properties
1)  It is soluble in DMF, DMSO, etc.
2)  Sealed storage at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis
2) It can be used to synthesize superamolecuar Ring: c-P12-(T6)2 [r4]
Characterization
HNMR
MS
FTIR
NA
HPLC
NA
Reference
1) Hoffmann, Markus; Karnbratt, Joakim; Chang, Ming-Hua; Herz, Laura M.; Albinsson, Bo; Anderson, Harry L.; Angewandte Chemie, International Edition 2008, 47(27), 4993-4996, DOI: 10.1002/anie.200801188 ; Enhanced π conjugation around a porphyrin[6] nanoring
2)  Lovett, Janet E.; Hoffmann, Markus; Cnossen, Arjen; Shutter, Alexander T. J.; Hogben, Hannah J.; Warren, John E.; Pascu, Sofia I.; Kay, Christopher W. M.; Timmel, Christiane R.; Anderson, Harry L.;  Journal of the American Chemical Society 2009, 131(38), 13852-13859, DOI: 10.1021/ja905796z ; Probing flexibility in porphyrin-​based molecular wires using double electron electron resonance
3) Zheng, Yao-Rong; Zhao, Zhigang; Kim, Hyunuk; Wang, Ming; Ghosh, Koushik; Pollock, J. Bryant; Chi, Ki-Whan; Stang, Peter J.; Inorg. Chem. 2010, 49(22), 10238-10240, DOI: 10.1021/ic1018373 ; Coordination-​Driven Self-​Assembly of Truncated Tetrahedra Capable of Encapsulating 1,​3,​5-​Triphenylbenzene
4) O'Sullivan, Melanie C.; Sprafke, Johannes K.; Kondratuk, Dmitry V.; Rinfray, Corentin; Claridge, Timothy D. W.; Saywell, Alex; Blunt, Matthew O.; O'Shea, James N.; Beton, Peter H.; Malfois, Marc; Anderson, Harry L.; Nature 2017, 541(7636), 200-203, DOI: 10.1038/nature09683 ; Vernier templating and synthesis of a 12-​porphyrin nano-​ring
5) 
6) Bols, Pernille S.; Rickhaus, Michel; Tejerina, Lara; Gotfredsen, Henrik; Eriksen, Kristina; Jirasek, Michael; Anderson, Harry L. ;  Journal of the American Chemical Society 2020, 142(30), 13219-13226, DOI: 10.1021/jacs.0c06269 ; Allosteric Cooperativity and Template-​Directed Synthesis with Stacked Ligands in Porphyrin Nanorings
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