Product Name：N,N'-bis(4-pyridyl formamide)-1,4-benzene
Synonymous：bpfb;
CAS：55119-42-1
Synonymous：bpfb;
CAS：55119-42-1
Basic Info
| M.F. | C18H14N4O2 | M.W. | 318.32936 | ||
| Appearance | |||||
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis：Hg(bpfb)I2 [r1] TMU-23 [r4]
Characterization
Reference
1) Niu, Y.; Song, Y.; Wu, J.; Hou, H.; Zhu, Y.; Wang, X.; Inorg. Chem. Commun. 2004, 7(4), 471-474, DOI: 10.1016/j.inoche.2004.01.006 ; Nonlinear polymeric effect: synthesis, crystal structure and nonlinear optical properties of a new mercury iodide adduct polymer [Hg(bpfb)I2]n · 2DMF (bpfb=N,N′-bis(4-pyridyl formamide)-1,4-benzene)
2) Sarkar, M.; Biradha, K.; Cryst. Growth Des 2006, 6(1), 202-208, DOI: 10.1021/cg050292l ; Amide-to-Amide Hydrogen Bonds in the Presence of a Pyridine Functionality: Crystal Structures of Bis(pyridinecarboxamido)alkanes
3) Luo, F.; Zheng, J.; Batten, S.; Chem. Commun. 2007, (36), 3744-3746, DOI:10.1039/b706177c ; Unprecedented (3,4)-connected metal–organic frameworks (MOFs) with 3-fold interpenetration and considerable solvent-accessible void space
4) Safarifard, V.; Rodriguez-Hermida, S.; Guillerm, V.; Imaz, I.; Bigdeli, M.; Tehrani, A.; Juanhuix, J.; Morsali, A.; Casco, M.; Silvestre-Albero, J.; Ramos-Fernandez, E.; Maspoch, D.; Cryst. Growth Des. 2016, 16, 10, 6016-6023, DOI: 10.1021/acs.cgd.6b01054 ; Influence of the Amide Groups in the CO2/N2 Selectivity of a Series of Isoreticular, Interpenetrated Metal-Organic Frameworks
