Product: IRMOF-3
Synonyms: NH2BDC-MOF-5
CAS：473981-31-6
Basic Information
| Unit MF. | C24H5N3O13Zn4 | Unit MW. | 804.8688 | ||
| Coordination Metal | Zn | Linkers | 2-Amino Terephthalic Acid（CAS：10312-55-7） | ||
| Aperture | 1.5 nm | Pore volume | |||
| Surface Area | BET >2000m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | Light Organce Powder |  |
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| Particle Size | irregular bulk particles | |||
Stability
1) IRMOF-3 could be stable in air for weeks; instable in aqueous conditions
2）Thermal decomposition temperature above 300 ° C
2）Thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 100 degree in vacuum.
Other Features
Fluorescence: 460nm fluorescence excited by 340nm UV light
Applications
1) Gas and pollutant adsorption
2) Good drug carrier, which is able to decompose in stomach and release the drug content
2) Good drug carrier, which is able to decompose in stomach and release the drug content
3) Lewis acid catalyst for irganic reactions, e.g. Knoevenagel condensation
Characterizations
References
1) M. Eddaoudi, J. Kim1, N. Rosi, D. Vodak, J. Wachter, M. O'Keeffe, O. M. Yaghi, Science 2002, 295(5554), 469-472, DOI: 10.1126/science.1067208 ; Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
2) Wei, J.-Z., Wang, X.-L., Sun, X.-J., Dong, H., Zhang, F.-M., Inorg. Chem. 2018, 57, 3818-3824, DOI: 10.1021/acs.inorgchem.7b03174 ; Rapid and Large-Scale Synthesis of IRMOF-3 by Electrochemistry Method with Enhanced Fluorescence Detection Performance for TNP；
3) Jesse L. C. Rowsell, Omar M. Yaghi; J. AM. CHEM. SOC., 2006, 128, 4; DOI：10.1021/ja056639q; Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal-Organic Frameworks；
4) David Britt, David Tranchemontagne, Omar M. Yaghi; PNAS, 2008, 105, 33; DOI：10.1073/pnas.0804900105; Metal-organic frameworks with high capacity and selectivity for harmful gases；
5）Zhenqiang Wang, Seth M. Cohen*; J. AM. CHEM. SOC., 2007, 129, 41; DOI：10.1021/ja074366o; Postsynthetic Covalent Modification of a Neutral Metal-Organic Framework；
6）Joseph G. Nguyen, Seth M. Cohen*;J. AM. CHEM. SOC., 2010, 132, 13; DOI：10.1021/ja100900c; Moisture-Resistant and Superhydrophobic Metal-Organic Frameworks Obtained via Postsynthetic Modification；
