Product: MIL-47
Synonyms: V(OH){O2C-C6H4-CO2}
CAS：NA
Basic Information
| Unit MF. | C8H4O5V | Unit MW. | 231.06 | ||
| Coordination Metal | Vanadium | Linkers |
Terephthalic acid |
||
| Pore Size | 0.85 nm channels | Pore volume | NA | ||
| Surface Area | >800m2/g | ||||
| Analog Structure | NA | ||||
Product Property
| Appearance | light yellow crystals/powders | |||
| Particle Size | NA | |||
Stability
1) MIL-47 could keep stable in air and solutions.
2) Thermal decomposition temperature >300℃. At above 300℃, MIL-47α loss of guest terephthalic acid to form MIL-47, and MIL-47 will decompose further at 673K.
2) Thermal decomposition temperature >300℃. At above 300℃, MIL-47α loss of guest terephthalic acid to form MIL-47, and MIL-47 will decompose further at 673K.
Preservation
1) Keep in a dry condition at room temperature.
2) It is recommended to activate it in a vacuum oven at room temperature for 3 hours before use.
Other Features
1) Fluorescence: NA
2) The framework is remarkably flexible, and the adsorption - desorption of gases can be monitored by X-ray diffraction at room temperature.
3) It has magnetic properties. MIL-47as exhibits antiferromagnetic behavior below \(T_{N}=95(5)K\), and the \(T_{N}\) of MIL-47 is 75(5)K.
2) The framework is remarkably flexible, and the adsorption - desorption of gases can be monitored by X-ray diffraction at room temperature.
3) It has magnetic properties. MIL-47as exhibits antiferromagnetic behavior below \(T_{N}=95(5)K\), and the \(T_{N}\) of MIL-47 is 75(5)K.
Applications
1) For the vapor-phase adsorption and separation of xylene isomers to achieve the separation of different isomers.
2) used for the adsorption and separation of gases, especially for the separation of C8 alkylaromatic components (such as toluene, xylenes, and ethylbenzene): The literature mentions research on the adsorption and separation of C8 alkylaromatic components under gas-phase conditions.
3) Its magnetic properties can be used in related fields such as magnetic separation.
2) used for the adsorption and separation of gases, especially for the separation of C8 alkylaromatic components (such as toluene, xylenes, and ethylbenzene): The literature mentions research on the adsorption and separation of C8 alkylaromatic components under gas-phase conditions.
3) Its magnetic properties can be used in related fields such as magnetic separation.
Characterizations
References
1) Finsy, Vincent; Verelst, Harry; Alaerts, Luc; De Vos, Dirk; Jacobs, Pierre A.; Baron, Gino V.; Denayer, Joeri F. M.; J. Am. Chem. Soc., 2008, 130(22), DOI: 10.1021/ja800686c; Pore-Filling-Dependent Selectivity Effects in the Vapor-Phase Separation of Xylene Isomers on the Metal-Organic Framework MIL-47
2) Bourrelly, Sandrine; Llewellyn, Philip L.; Serre, Christian; Millange, Franck; Loiseau, Thierry; Férey, Gérard; J. Am. Chem. Soc., 2005, 127(39), DOI: 10.1021/ja054668v; Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47
3) Barthelet, Karin; Marrot, Jérôme; Riou, Didier; Férey, Gérard; Angew. Chem. Int. Ed., 2002, 41(2), DOI: 10.1002/1433-7851(20020115)41:23.0.CO;2-7; A Breathing Hybrid Organic–Inorganic Solid with Very Large Pores and High Magnetic Characteristics；
4) Lomig Hamon, Christian Serre, Thomas Devic, Thierry Loiseau, Franck Millange, Gérard Férey, Guy De Weireld. Journal of the American Chemical Society, 2009, 131, 25; DOI: 10.1021/ja901587t. Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal-Organic Frameworks at Room Temperature.
