Product：CTF-1
Synonyms：CTF-CN
CAS：2155822-92-5 or 2173362-13-3
Synonyms：CTF-CN
CAS：2155822-92-5 or 2173362-13-3
Basic Information
| Unit MF. | C40H24N2 | Unit MW. | 532.66 | ||
| Linkers |
Benzene-1,4-dicarboximidamide dihydrochloride CAS: 14401-56-0; 1,4-Phthalaldehyde CAS: 623-27-8 |
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| Aperture | 1.2 nm | Pore volume | 0.40 cm3/g | ||
| Surface Area | BET Specific surface >900m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance |
Black solid |
 |
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| Particle Size | irregular particle clusters | |||
Stability
1) Py-COF is stable in air and acqeous solutions (PH 1-14)
2) Thermal decomposition temperature above 400 degree
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) Heated in vacuum at 150 for 2-3 hours
Other Features
Fluorescence: NA
Applications
1) For gas and pollutant adsorption
2) Rigid pores can be used to load other catalysts
2) Rigid pores can be used to load other catalysts
3) Good photocatalytical capbility for hydrogen evolution
Characterizations
References
1) P. Kuhn, M. Antonietti, A. Thomas, Angew. Chem. Int. Ed. 2008, 47, 3450–3453, DOI: 10.1002/anie.200705710 ; Porous, Covalent Triazine‐Based Frameworks Prepared by Ionothermal Synthesis【文献解读】
2) Tian Sun, Yan Liang, Prof. Yuxi Xu, Angew. Chem. Int. Ed.2022,61, e202113926, DOI: 10.1002/anie.202113926 ; Rapid, Ordered Polymerization of Crystalline Semiconducting Covalent Triazine Frameworks
3) Tian Sun, Yan Liang, Wenjia Luo, Lei Zhang, Xiaofeng Cao, Prof. Yuxi Xu, DOI: 10.1002/anie.202203327 ; A General Strategy for Kilogram-Scale Preparation of Highly Crystal-line Covalent Triazine Frameworks
4) Congxu Wang, Pengbo Lyu, Zhong Chen, and Yuxi Xu, J. Am. Chem. Soc. 2023, 145, 23, 12745-12754, DOI: 10.1021/jacs.3c02874 ; Green and Scalable Synthesis of Atomic-Thin Crystalline Two-Dimensional Triazine Polymers with Ultrahigh Photocatalytic Properties；
5）Sara Abednatanzi,⊥ Parviz Gohari Derakhshandeh,⊥ Sasanka Dalapati, Savita K. P. Veerapandian, Anne-Claire Froissart, Jan Dirk Epping, Rino Morent, Nathalie De Geyter, and Pascal Van Der Voort; ACS Appl. Mater. Interfaces 2022, 14, 15287−15297; DOI：10.1021/acsami.2c01091; Metal-Free Chemoselective Reduction of Nitroarenes Catalyzed by Covalent Triazine Frameworks: The Role of Embedded Heteroatoms【文献解读】
