Product: SIFSIX-1-Cu
Synonyms: [CuSiF6(4,4'-bpy)2].8H2O
CAS：288297-89-2
Basic Information
| Unit MF. | C20H8N4F6SiCu | Unit MW. | 509.93 | ||
| Coordination Metal | Cu | Linkers |
4,4’-BiPyridine（CAS：553-26-4） |
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| Pore Size | 0.8nm | Pore volume | 0.55 cm3/g | ||
| Surface Area | NA | ||||
| Analog Structure |   |
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Product Property
| Appearance | Blue Powders |  |
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| Particle Size | irregular bulk particles | |||
Stability
1) SIFSIX-1-Cu is stable in organic solution(e.g. methanol) for weeks.
2) Thermal decomposition temperature about 150 ° C
2) Thermal decomposition temperature about 150 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate 12 hours at room temperature in vacuum
Other Features
Fluorescence:NA
Applications
1) Gas adsorption (e.g. CO2, SO2)
Characterizations
References
1) Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.; Cairns, Amy J.; Luebke, Ryan; Forrest, Katherine; Pham, Tony; Ma, Shengqian; Space, Brian; Wojtas, Lukasz; Eddaoudi, Mohamed; Zaworotko, Michael J.; Nature 2013), 495(7439), 80-84, DOI: 10.1038/nature11893 ; Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
2) Qian, Siheng; Xia, Ling; Yang, Lifeng; Wang, Xiaobing; Suo, Xian; Cui, Xili; Xing, Huabin From Journal of Membrane Science (2020)611, 118329, DOI: 10.1016/j.memsci.2020.118329 ; Defect-free mixed-matrix membranes consisting of anion-pillared metal-organic frameworks and poly(ionic liquid)s for separation of acetylene from ethylene；
3）Xili Cui, Kaijie Chen, Huabin Xing, Qiwei Yang, Rajamani Krishna, Zongbi Bao, Hui Wu, Wei Zhou, Xinglong Dong, Yu Han, Bin Li, Qilong Ren, Michael J. Zaworotko, Banglin Chen. Science, 2016, 353, 6295, 141-145. DOI:10.1126/science.aaf2458. Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene；
4）Shin-ichiro Noro, Susumu Kitagawa, Mitsuru Kondo, Kenji Seki; Angewandte Chemie, International Edition (2000), 39(12), 2082-2084; https://doi.org/10.1002/1521-3773(20000616)39:12<2081::AID-ANIE2081>3.0.CO;2-A; A New, Methane Adsorbent, Porous Coordination Polymer [{CuSiF₆(4,4-bipyridine)₂}]ₙ；
5）Stephen D. Burd, Shengqian Ma, Jason A. Perman, Benjamin J. Sikora, Randall Q. Snurr, Praveen K. Thallapally, Jian Tian, Lukasz Wojtas, Michael J. Zaworotko, *Journal of the American Chemical Society*, 2012, 134, 3663-3666, DOI:10.1021/ja211340t, Paper title: Highly Selective Carbon Dioxide Uptake by [Cu(bpy-n)₂(SiF₆)] (bpy-1=4,4'-Bipyridine; bpy-2=1,2-Bis(4-pyridyl)ethene)；
6）Guining Chen, Cailing Chen, Yanan Guo, Zhenyu Chu, Yang Pan, Guozhen Liu, Gongping Liu, Yu Han, Wanqin Jin, Nanping Xu, *Science*, 2023, 381, 1350-1356, DOI:10.1126/science.adi1545, Paper title:Solid-solvent processing of ultrathin, highly loaded mixed-matrix membrane for gas separation；
7）Yang, L. F., Cui, X. L., Yang, Q. W., Qian, S. H., Wu, H., Bao, Z. B., Zhang, Z. G., Ren, Q. L., Zhou, W., Chen, B., Xing, H. B. (2018). Advanced Materials, 30(1), 1705374. DOI: 10.1002/adma.201705374; A Single-Molecule Propyne Trap: Highly Efficient Removal of Propyne from Propylene with Anion-Pillared Ultramicroporous Materials;
8) Daniel O’Nolan, Amrit Kumar, Michael J. Zaworotko*; Journal of the American Chemical Society, 2017, 139, 8508-8513; DOI：10.1021/jacs.7b01682; Water Vapor Sorption in Hybrid Pillared Square Grid Materials;
9) Katherine A. Forrest, Tony Pham, Brian Space;CrystEngComm, 2017, 19, 3338-3347;DOI ：10.1039/c7ce00594f;Comparing the mechanism and energetics of CO₂ sorption in the SIFSIX series
