Product Name：4,4'-Bi-1H-pyrazole
Synonymous：H2BPZ
CAS：25240-33-9
Synonymous：H2BPZ
CAS：25240-33-9
Basic Info
| M.F. | C6H6N4 | M.W. | 134.13864 | ||
| Appearance |  |
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Properties
1) It is soluble in DMF, DMSO, etc.
2) Sealed storage at room temperature
2) Sealed storage at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[M(BPZ)]·Solv (M = Zn, Co, Cd, Hg, Cu, Ni…) [r2] ; CFA-10-as [r3]
Characterization
Reference
1) Boldog, I.; Rusanov, E.; Chernega, A.; Sieler, J.; Domasevitch, K.; Angew. Chem., Int. Ed 2001, 40(18), 3435-3438, DOI:10.1002/1521-3773(20010917)40:18<3435::AID-ANIE3435>3.0.CO;2-M ; Acentric Extended Solids by Self Assembly of 4,4′‐Bipyrazolyls
2) Pettinari, C.; Tabacaru, A.; Boldog, I.; Domasevitch, K.; Galli, S.; Masciocchi, N.; Inorg. Chem. 2012, 51(9), 5235-5245, DOI: 10.1021/ic3001416 ; Novel Coordination Frameworks Incorporating the 4,4′-Bipyrazolyl Ditopic Ligand
3) Spirkl, S.; Grzywa, M.; Reschke, S.; Fischer, J.; Sippel, P.; Demeshko, S.; Krug von Nidda, H.; Volkmer, D.; Inorg. Chem. 2017, 56(20), 12337-12347, DOI:10.1021/acs.inorgchem.7b01818 ; Single-Crystal to Single-Crystal Transformation of a Nonporous Fe(II) Metal–Organic Framework into a Porous Metal–Organic Framework via a Solid-State Reaction
