Product Name：1,1,2,2-tetrakis[4-phosphonophenyl]ethylene
Synonymous：H8TPPE;tetraphenylethylene tetraphosphonic acid
CAS：2485827-21-0
3) Steinke, Felix; Javed, Ali; Woehlbrandt, Stephan; Tiemann, Michael; Stock, Norbert; Dalton Trans. 2021, 50(38), 13572-13579, DOI: 10.1039/d1dt02610k ; New isoreticular phosphonate MOFs based on a tetratopic linker
4) Chakraborty, Debabrata; Bej, Sourav; Sahoo, Sumanta; Chongdar, Sayantan; Ghosh, Anirban; Banerjee, Priyabrata; Bhaumik, Asim; ACS Sustainable Chem. & Eng. 2021, 9(42), 14224-14237, DOI: 10.1021/acssuschemeng.1c04877 ; Novel Nanoporous Ti-Phosphonate Metal-Organic Framework for Selective Sensing of 2,4,6-Trinitrophenol and a Promising Electrode in an Energy Storage Device
Synonymous：H8TPPE;tetraphenylethylene tetraphosphonic acid
CAS：2485827-21-0
Basic Info
| M.F. | C26H24O12P4 | M.W. | 652.35676 | ||
| Appearance | |||||
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[Ni2(H4TPPE)(H2O)6]·4H2O / CAU-46 , [Co2(H4TPPE)(H2O)4]·3H2O / CAU-47 [r1]; M-CAU-53 (M = Al3+, Ga3+, Fe3+) [r3];
Characterization
Reference
1) Woehlbrandt, Stephan; Meier, Christoph; Reinsch, Helge; Svensson Grape, Erik; Inge, A. Ken; Stock, Norbert; Inorg. Chem. 2020, 59(18), 13343-13352, DOI: 10.1021/acs.inorgchem.0c01703 ; A Tetratopic Phosphonic Acid for the Synthesis of Permanently Porous MOFs: Reactor Size-Dependent Product Formation and Crystal Structure Elucidation via Three-Dimensional Electron Diffraction
2) Chakraborty, Debabrata; Ghorai, Arijit; Chowdhury, Avik; Banerjee, Susanta; Bhaumik, Asim; Chem.-Asian J. 2021, 16(12), 1562-1569, DOI: 10.1002/asia.202100270 ; A Tetradentate Phosphonate Ligand-based Ni-MOF as a Support for Designing High-performance Proton-conducting Materials