Product: TFPA-TAPT COF
Synonyms: TPA-TCIF COF
CAS：2268016-66-4
Basic Information
| Unit MF. | (C21H18N6.C21H15NO3)x | Unit MW. | 683.76 | ||
| Linkers |
1) 4,4',4''-Nitrilotribenzaldehyde （CAS: 119001-43-3） 2) (1,3,5-tris-(4-aminophenyl)triazine (CAS:14544-47-9) |
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| Aperture | 1.5 nm | Pore volume | 1.23 cm³/g | ||
| Surface Area | BET比表面积为2900 m²/g | ||||
| Analog Structure | |||||
Product Property
| Appearance | Cauliflower like morphology | |||
| Particle Size | / | |||
Stability
1) It exhibits high stability in water and various organic solvents;
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) Activation method: TPA-TCIF is vacuum dried at 200 ° C in an inert atmosphere for 10 hours
2) Activation method: TPA-TCIF is vacuum dried at 200 ° C in an inert atmosphere for 10 hours
Other Features
Fluorescence:NA
Applications
1) It can be used for gas storage and separation;
2) The imine group has Lewis alkalinity and can be used as a catalyst or catalyst carrier;
3) It can serve as a carrier for drug molecules, used for targeted drug delivery and controlled release;
4) It can be used for water treatment and pollutant adsorption, such as removing heavy metal ions and organic pollutants from water;
Characterizations
References
1) Puthiaraj, Pillaiyar; Kim, Hyun Sub; Yu, Kwangsun; Ahn, Wha-Seung; Microporous and Mesoporous Materials 2020 , 297, 110011pp; DOI: 10.1016/j.micromeso.2020.110011 ; Triphenylamine-based covalent imine framework for CO2 capture and catalytic conversion into cyclic carbonates
2) Puthiaraj, Pillaiyar; Yu, Kwangsun; Shim, Sang Eun; Ahn, Wha-Seung;Molecular Catalysis 2019 , 473, 110395 ; DOI: 10.1016/j.mcat.2019.110395 ;Pd(II)-immobilized on a nanoporous triazine-based covalent imine framework for facile cyanation of haloarenes with K4Fe(CN)6
2) Puthiaraj, Pillaiyar; Yu, Kwangsun; Shim, Sang Eun; Ahn, Wha-Seung;Molecular Catalysis 2019 , 473, 110395 ; DOI: 10.1016/j.mcat.2019.110395 ;Pd(II)-immobilized on a nanoporous triazine-based covalent imine framework for facile cyanation of haloarenes with K4Fe(CN)6
