Product: HKUST-1
Synonyms: Cu-BTC; BASOLite C300；MOF-199
CAS：222404-02-6
Basic Information
| Unit MF. | C18H9O15Cu3 | Unit MW. | 655.89 | ||
| Coordination Metal | Cu | Linkers | 1,3,5-Benzenetricarboxylic acid (CAS:554-95-0) | ||
| Aperture | 0.9nm | Pore volume | 0.33 cm3/g | ||
| Surface Area | BET Specific surface 1500 m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | Blue Powder |  |
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| Particle Size | 100-200nm; 500nm; 1um; 5um | |||
Stability
1) HKUST-1 is stable in air；intable in aqueous or wet/moisture conditions (for application of HKUST-1/Cu-BTC structure in wet condition of solutions, please refer to a modified structure of HKUST-1 as Cu-BTC-IPA)
2) Thermal decomposition temperature around 240 ° C
2) Thermal decomposition temperature around 240 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) Open Cu2+ sites for catalysis utility
2) Open Cu2+ sites for catalysis utility
Characterizations
References
1）Stephen S.-Y. Chui, Samuel M.-F. Lo, Jonathan P. H. Charmant, A. Guy Orpen and Ian D. Williams; Science 283 (5405), 1148-1150；
2）Zhang, W., Hu, Y. L., Ge, J., Jiang, H. L., & Yu, S. H. (2014); Journal of the American Chemical Society, 136(49), 16978-16981; DOI: 10.1021/ja509960n; A Facile and General Coating Approach to Moisture/Water-Resistant Metal-Organic Frameworks with Intact Porosity.;
3) Fei Ke, Yu-Peng Yuan, Ling-Guang Qiu*, Yu-Hua Shen, An-Jian Xie, Jun-Fa Zhu, Xing-You Tian, Li-De Zhang; Journal of Materials Chemistry, 2011, 21, 3843; DOI: 10.1039/c0jm01770a; Facile fabrication of magnetic metal–organic framework nanocomposites for potential targeted drug delivery.;
4) Bo Xiao, Paul S. Wheatley, Xuebo Zhao, Ashleigh J. Fletcher, Sarah Fox, Adriano G. Rossi, Ian L. Megson, S. Bordiga, L. Regli, K. Mark Thomas, Russell E. Morris; J. AM. CHEM. SOC. 2007, 129, 1203-1209 9 1203; DOI: 10.1021/ja066098k; High-Capacity Hydrogen and Nitric Oxide Adsorption and Storage in a Metal-Organic Framework.;
5) Biemmi E, Scherb C, Bein T. J. Am. Chem. Soc., 2007, 129, 26, 8054–8055. DOI: 10.1021/ja0701208. Oriented Growth of the Metal Organic Framework Cu₃(BTC)₂(H₂O)₃·xH₂O Tunable with Functionalized Self-Assembled Monolayers.;
6) Fei Ke, Ling-Guang Qiu, Yu-Peng Yuan, Fu-Min Peng, Xia Jiang, An-Jian Xie, Yu-Hua Shen, Jun-Fa Zhu; Journal of Hazardous Materials (2011), 196, 36-43; DOI：10.1016/j.jhazmat.2011.08.069; Thiol-functionalization of metal-organic framework by a facile coordination-based postsynthetic strategy and enhanced removal of Hg²⁺ from water；
7）Jie Song, Zhen Luo, David K. Britt, Hiroyasu Furukawa, Omar M. Yaghi, Kenneth I. Hardcastle, Craig L. Hill; J. Am. Chem. Soc., 2011, 133, 16839–16846; DOI: 10.1021/ja203695h; A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate-Metal Organic Framework for Aerobic Decontamination
