Product Name:5,10,15,20-Tetrakis(4-aminophenyl)-21H,23H-porphine
Synonymous:H2TAPP; Tph
CAS:22112-84-1
Synonymous:H2TAPP; Tph
CAS:22112-84-1
Basic Info
M.F. | C44H34N8 | M.W. | 674.79436 | ||
Appearance | ![]() |
Properties
1) TAPP is soluble in chloroform, DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for COF synthesis:COF-366 [r2]; H2P-Bph-COF [r4]; PI-COF/PI-CONs [r5]; DmaTPh DhaTPh [r3]
Characterization
Reference
1) Treibs, A.; Haeberle, N.; Justus Liebigs Annalen der Chemie 1968, 718, 183-207
2) Wan, S.; Gandara, F.; Asano, A.; Furukawa, H.; Saeki, A.; Dey, S.; Liao, L.; Ambrogio, M.; Botros, Y.; Duan, X.; Seki, S.; Stoddart, J.; Yaghi, O. Chem. Mater. 2011, 23, 4094– 4097, DOI:10.1021/cm201140r ; Covalent Organic Frameworks with High Charge Carrier Mobility
3) Kandambeth, S.; Shinde, D.; Panda, M.; Lukose, B.; Heine, T.; Banerjee, R.; Angew. Chem., Int. Ed. 2013, 52(49), 13052-13056, DOI: 10.1002/anie.201306775 ; Enhancement of Chemical Stability and Crystallinity in Porphyrin‐Containing Covalent Organic Frameworks by Intramolecular Hydrogen Bonds
4) Hou, Y.; Zhang, X.; Sun, J.; Lin, S.; Qi, D.; Hong, R.; Li, D.; Xiao, X.; Jiang, J.; Microp. Mesop. Mater. 2015, 214, 108-114, DOI:10.1016/j.micromeso.2015.05.002 ; Good Suzuki-coupling reaction performance of Pd immobilized at the metal-free porphyrin-based covalent organic framework
5) Zhang, C.; Zhang, S.; Yan, Y.; Xia, F.; Huang, A.; Xian, Y.; ACS Appl. Mater. Interfaces 2017, 9(15), 13415-13421, DOI:10.1021/acsami.6b16423
HNMR-22112-84-1-CS013117.pdf | Download |
22112-84-1-CS013539-HNMR.pdf | Download |
22112-84-1-CS013837.pdf | Download |
22112-84-1-CS013887.pdf | Download |
22112-84-1-CS016044.pdf | Download |
22112-84-1-CS016082.pdf | Download |
22112-84-1-CS014344.pdf | Download |
22112-84-1-CS014765.pdf | Download |
22112-84-1-CS014849.pdf | Download |
22112-84-1-CS014994.pdf | Download |
22112-84-1-CS017043.pdf | Download |
22112-84-1-CS017334.pdf | Download |
22112-84-1-CS017333.pdf | Download |
22112-84-1-CS017876.pdf | Download |
22112-84-1-CS018349.pdf | Download |
22112-84-1-CS018358.pdf | Download |
22112-84-1 -CS013918-HPLC.pdf | Download |