Product: MOF-808(Zr)
Synonyms: NA
CAS：1579984-19-2
Basic Information
| Unit MF. | C24H2O32Zr6 | Unit MW. | 1348.589 | ||
| Coordination Metal | Zr Clusters | Linkers | benzene-1,3,5-tricarboxylic acid (CAS: 554-95-0) | ||
| Aperture | 0.48nm; 1.84nm | Pore volume | 0.84 cm3/g (Vmicropore: 0.59 cm3/g) | ||
| Surface Area | BET Specific surface >1400 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Off-White Powder |  |
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| Particle Size | <200nm | |||
Stability
1) MOF-808 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2) High thermal stability, thermal decomposition temperature above 400 ° C
2) High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to degass at 120 degree for 12 hours in vacuum
2) It is recommended to degass at 120 degree for 12 hours in vacuum
3) Ultrasonic dispersion in methanol/ethanol/DMF
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) Catalyical activity, such as Peroxidase-Like Catalytic Activity [r4]
2) Catalyical activity, such as Peroxidase-Like Catalytic Activity [r4]
Characterizations
References
1) Furukawa, H.; Gándara, F.; Zhang, Y.-B.; Jiang, J.; Queen, W. L.; Hudson, M.R.; Yaghi, O.M.; J. Am. Chem. Soc. 2014, 136, 4369-4381, DOI: 10.1021/ja500330a ; Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
2) Jiang, J.; Gándara, F.; Zhang, Y.; Na, K.; Yaghi, O.; Klemperer, W.; J. Am. Chem. Soc. 2014, 136, 37, 12844–12847, DOI: 10.1021/ja507119n ; Superacidity in Sulfated Metal–Organic Framework-808
3) Yang, P.; Shu, Y.; Zhuang, Q.; Li, Y.; Gu, J.; Langmuir 2019, 35, 49, 16226-16233, DOI: 10.1021/acs.langmuir.9b03057 ; Metal–Organic Frameworks Bearing Dense Alkyl Thiol for the Efficient Degradation and Concomitant Removal of Toxic Cr(VI)
4) Zheng, H.; Liu, C.; Zeng, X.; Chen, J.; Lü, J.; Lin, R.; Cao, R.; Lin, Z.; Su, J.; Inorg. Chem. 2018, 57, 15, 9096–9104, DOI: 10.1021/acs.inorgchem.8b01097 ; MOF-808: A Metal–Organic Framework with Intrinsic Peroxidase-Like Catalytic Activity at Neutral pH for Colorimetric Biosensing
