Product: HOF-14
Synonyms: HOF-102
CAS:NA
Basic Information
Unit MF. | C60H34O8 | Unit MW. | 882.90716 | ||
Linkers | 6,60,600,60 0 0-(Pyrene-1,3,6,8-tetrayl)tetrakis(2-naphthoic acid) / H4PTTNA (CAS: 2010983-66-9) | ||||
Pore Size | 3.0nm, 2.5nm; Interlayer distance 3.7 nm | Pore volume | 1.35 cm3/g | ||
Surface Area | BET Specific surface 2500 m2/g, | ||||
Analog Structure | ![]() |
Product Property
Appearance | Yellow Powder | ![]() |
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Particle Size | 20-30 um rodlike particles or wires |
Stability
1) HOF-14/HOF-102 is one of the most stable organic frameworks
2) HOF-102/HOF-14 is extremly stable in air, stable in aqueous and boiling water. It is also stable acidic and baseconditions (stable in PH 0-14)
3) High thermal stability, thermal decomposition temperature above 400 ° C
3) High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 6 hours at 120 degree in vacuum
2) It is recommended to activate for 6 hours at 120 degree in vacuum
Other Features
NA
Applications
1) With large pore size above 3.0 nm, HOF-102/HOF-14 is potential material for adsorption of large moleculars, including drug moleculars, RNA and enzyme. It is especially propespctive in enzyme fixation.
2) With rigid framework, HOF-102/HOF-14 is good carrier of catalyst. It is potential material for storage of gas, pollutes and small moleculars.
3) HOF-102 is easily composed with text fibers. It is prospective in application of flexible applicance and sensors.
Characterizations
References
1) Ma, K.; Li, P.; Xin, J.; Chen, Y.; Chen, Z.; Goswami, S.; Liu, X.; Kato, S.; Chen, H.; Zhang, X.; Bai, J.; Wasson, Me.; Maldonado, R.; Snurr, R.; Farha; O.; Cell Reports Physical Science 2020, 1, 100024, DOI:10.1016/j.xcrp.2020.100024 ; Ultrastable Mesoporous Hydrogen-Bonded Or-ganic Frameworks Based Fiber Composites To-ward Mustard Gas Detoxification
2) Wang, B.; Lv, X.; Lv, J.; Ma, L.; Lin, R.; Cui, H.; Zhang, J.; Zhang, Z.; Xiang, S.; Chen, B.; Chem. Commun., 2020, 56, 66-69, DOI: 10.1039/c9cc07802a ; A novel mesoporous hydrogen-bonded organic framework with high porosity and stability
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