Product Name：Potassium hydrotris(pyrazolyl)borate
Synonymous：KBPyz3;Borate(1-), hydrotris(1H-pyrazolato-N1)-, potassium, (T-4)-; Borate(1-), hydrotris(1H-pyrazolato-κN1)-, potassium, (T-4)- (9CI); Borate(1-), hydrotris(pyrazolato)-, potassium (8CI); 1H-Pyrazole, boron complex; Potassium hydridotris(1-pyrazolyl)borate; Potassium hydrotripyrazolylborate; Potassium hydrotris(1-pyrazolyl)borate; Potassium hydrotris(1-pyrazolyl)borate(1-); Potassium hydrotris(1H-pyrazol-1-yl)borate; Potassium hydrotris(pyrazol-1-yl)borate; Potassium hydrotris(pyrazolato)borate; Potassium hydrotris(pyrazolato)borate(1-);
CAS：18583-60-3
3) Comito, Robert J.; Wu, Zhenwei; Zhang, Guanghui; Lawrence, John A. III; Korzynski, Maciej D.; Kehl, Jeffrey A.; Miller, Jeffrey T.; Dinca, Mircea; Angew. Chem., Int. Ed. 2018, 57(27), 8135-8139, DOI: 10.1002/anie.201803642 ; Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal-Organic Framework
4) Murtuza, Shahid; Casagrande, Osvaldo L., Jr.; Jordan, Richard F.; Organometallics 2002, 21(9), 1882-1890, DOI: 10.1021/om010530j ; Ethylene Polymerization Behavior of Tris(pyrazolyl)borate Titanium(IV) Complexes
Synonymous：KBPyz3;Borate(1-), hydrotris(1H-pyrazolato-N1)-, potassium, (T-4)-; Borate(1-), hydrotris(1H-pyrazolato-κN1)-, potassium, (T-4)- (9CI); Borate(1-), hydrotris(pyrazolato)-, potassium (8CI); 1H-Pyrazole, boron complex; Potassium hydridotris(1-pyrazolyl)borate; Potassium hydrotripyrazolylborate; Potassium hydrotris(1-pyrazolyl)borate; Potassium hydrotris(1-pyrazolyl)borate(1-); Potassium hydrotris(1H-pyrazol-1-yl)borate; Potassium hydrotris(pyrazol-1-yl)borate; Potassium hydrotris(pyrazolato)borate; Potassium hydrotris(pyrazolato)borate(1-);
CAS：18583-60-3
Basic Info
| M.F. | C9H10BN6-.K+ | M.W. | 252.1252 | ||
| Appearance | |||||
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis：Poly(1-pyrazolyl)-borates
Characterization
Reference
1) Trofimenko, Swiatoslaw; J. Am. Chem. Soc. 1967, 89(13), 3170-3177, DOI: 10.1021/ja00989a017 ; Boron-pyrazole chemistry. II. Poly(1-pyrazolyl)-borates
2) Sohrin, Yoshiki; Kokusen, Hisao; Kihara, Sorin; Matsui, Masakazu; Kushi, Yoshihiko; Shiro, Motoo; J. Am. Chem. Soc. 1993, 115(10), 4128-4136, DOI: 10.1021/ja00063a034 ; New mode of ion size discrimination for Group 2 metals using poly(pyrazolyl)borate ligands. Control of stability and structure of chelate complexes by intraligand contact