Product: SIFSIX-3-Zn
Synonyms: [Zn(pz)2(SiF6)2]
CAS：1804924-64-8
Basic Information
| Unit MF. | C12H8N4SiF6Zn | Unit MW. | 367.65 | ||
| Coordination Metal | Zn | Linkers |
Pyrazine (CAS: 289-57-2) |
||
| Pore Size | ~0.3 nm | Pore volume | NA | ||
| Surface Area | NA | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | Pale Yellow Crystals | |||
| Particle Size | NA | |||
Stability
1) Stable in humid air and stable in water and ethanol
2) Thermal decomposition temperature not mentioned. However, column breakthrough experiments suggest that the material may undergo a phase change at high temperature and high humidity.
2) Thermal decomposition temperature not mentioned. However, column breakthrough experiments suggest that the material may undergo a phase change at high temperature and high humidity.
Preservation
1) Keep in dry and Cool Condition
2) Degassing the methanol-exchanged sample by heating at room temperature for 15 hours.
Other Features
NA
Applications
1) High selectivity for CO2 adsorption and separation
2) Efficient removal of CO2 from simulated flue gas
3) Application in gas separation (e.g., N2/CO2 separation)
2) Efficient removal of CO2 from simulated flue gas
3) Application in gas separation (e.g., N2/CO2 separation)
Characterizations
References
1) Elsaidi, Sameh K.; Mohamed, Mona H.; Schaef, Herbert T.; Kumar, Amrit; Lusi, Matteo; Pham, Tony; Forrest, Katherine A.; Space, Brian; Xu, Wenqian; Halder, Gregory J.; Liu, Jun; Zaworotko, Michael J.; Thallapally, Praveen K.; Chem. Commun., 2015, 51, 15530-15533, DOI: 10.1039/c5cc06577a, Hydrophobic pillared square grids for selective removal of CO2 from simulated flue gas；2) Gong, Heqing; Nguyen, Tien Hoa; Wang, Rong; Bae, Tae-Hyun; Journal of Membrane Science, 2015, 490, 108-117, DOI: 10.1016/j.memsci.2015.08.018; Separations of binary Mixtures of CO₂/CH₄ and CO₂/N₂ with mixed-matrix Membranes containing Zn(pyrz)₂(SiF₆) metal-organic framework;
3) Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.; Cairns, Amy J.; Luebke, Ryan; Forrest, Katherine; Pham, Tony; Ma, Shengqian; Space, Brian; Wojtas, Lukasz; Eddaoudi, Mohamed; Zaworotko, Michael J.; Nature 2013), 495(7439), 80-84, DOI: 10.1038/nature11893 ; Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation；
4）Xili Cui, Kaijie Chen, Huabin Xing, Qiwei Yang, Rajamani Krishna, Zongbi Bao, Hui Wu, Wei Zhou, Xinglong Dong, Yu Han, Bin Li, Qilong Ren, Michael J. Zaworotko, Banglin Chen. Science, 2016, 353, 6295, 141-145. DOI:10.1126/science.aaf2458. Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene;
5) Yang, L. F., Cui, X. L., Yang, Q. W., Qian, S. H., Wu, H., Bao, Z. B., Zhang, Z. G., Ren, Q. L., Zhou, W., Chen, B., Xing, H. B. (2018). Advanced Materials, 30(1), 1705374. DOI: 10.1002/adma.201705374; A Single-Molecule Propyne Trap: Highly Efficient Removal of Propyne from Propylene with Anion-Pillared Ultramicroporous Materials;
6) Katherine A. Forrest, Tony Pham, Sameh K. Elsaidi, Mona H. Mohamed, Praveen K. Thallapally, Michael J. Zaworotko, Brian Space; Crystal Growth & Design, 2019, 19, 3732-3743; DOI：10.1021/acs.cgd.9b00086; Investigating CO₂ Sorption in SIFSIX-3-M (M = Fe, Co, Ni, Cu, Zn) through Computational Studies;
7) Katherine A. Forrest, Tony Pham, Brian Space;CrystEngComm, 2017, 19, 3338-3347;DOI ：10.1039/c7ce00594f;Comparing the mechanism and energetics of CO₂ sorption in the SIFSIX series;
