Product: UIO-66(Ce)
Synonyms: Ce-UIO-66-BDC
CAS：1801427-51-9
Basic Information
| Unit MF. | C48H4O32Ce6 | Unit MW. | 1953.38 | ||
| Coordination Metal | Ce | Linkers | Terephthalic acid (CAS: 100-21-0) | ||
| Pore Size | 0.8nm; 1.1nm | Pore volume | 0.5 cm3/g | ||
| Surface Area | BET Specific surface 1100 m2/g, | ||||
| Analog Structure |  |
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Product Property
| Appearance | Pale Yellow Powders |  |
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| Particle Size | 50-200nm irregular nanoparticles | |||
Stability
1) Ce-UIO-66 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2) High thermal stability, thermal decomposition temperature above 400 ° C
2) High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption; UIO-66 has very rigid framework, which is good carrier of catalyst.
2) With special oxidation and reduction property of Ce+/Ce2+, Ce-UIO-66 could be used to catalyze oxidation reaction
2) With special oxidation and reduction property of Ce+/Ce2+, Ce-UIO-66 could be used to catalyze oxidation reaction
Characterizations
References
1) Lammert, Martin; Wharmby, Michael T.; Smolders, Simon; Bueken, Bart; Lieb, Alexandra; Lomachenko, Kirill A.; Vos, Dirk De; Stock, Norbert; Chem. Commun. 2015, 51(63), 12578-12581, DOI: 10.1039/C5CC02606G ; Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity;
2) Xin-Ping Wu, Laura Gagliardi, Donald G. Truhlar; Journal of the American Chemical Society, 2018, 140, 7904−7912; DOI：10.1021/jacs.8b03613; Cerium Metal−Organic Framework for Photocatalysis;
3) Mohamed H. Hassan, Robert Stanton, Jeremy Secora, Dhara J. Trivedi, Silvana Andreescu*; ACS Applied Materials & Interfaces, 2020, 12, 52788-52796; DOI：10.1021/acsami.0c16477; Ultrafast Removal of Phosphate from Eutrophic Waters Using a Cerium-Based Metal−Organic Framework;
4) Timur Islamoglu, Ahmet Atilgan, Su-Young Moon, Gregory W. Peterson, Jared B. DeCoste, Morgan Hall, Joseph T. Hupp, Omar K. Farha; Chemistry of Materials, 2017, 29, 2672-2675; DOI：10.1021/acs.chemmater.6b04835; Cerium(IV) vs Zirconium(IV) Based Metal−Organic Frameworks for Detoxification of a Nerve Agent;
