Product Name：1,1'-(Benzene-1,4-Diyldimethylene)-Bis(3,5-Dimethyl-1H-Pyrazole)
Synonymous：bdb；1,4-bis((3,5-dimethyl-1H-pyrazol-1-yl)methyl)benzene
CAS：172606-22-3
Synonymous：bdb；1,4-bis((3,5-dimethyl-1H-pyrazol-1-yl)methyl)benzene
CAS：172606-22-3
Basic Info
| M.F. | C18H22N4 | M.W. | 294.39408 | ||
| Appearance | |||||
Properties
1) It is soluble in DMF, DMSO, etc.
2) Sealed storage at room temperature
2) Sealed storage at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis：[Ag(μ-bpb)2] [r4]; [Cu(μ-bpb)2](PF6) [r5]
Characterization
Reference
1) Hartshorn, Chris M.; Steel, Peter J.; Australian J. Chem. 1995, 48(9), 1587-1599, DOI: 10.1071/CH9951587 ; Poly(pyrazol-1-ylmethyl)benzenes: new multidentate ligands
2) Wang, Xin-Yu; Liu, Shu-Qing; Zhang, Chun-Yan; Song, Ge; Bai, Feng-Ying; Xing, Yong-Heng; Shi, Zhan; Polyhedron 2012, 47(1), 151-164, DOI: 10.1016/j.poly.2012.08.016 ; Synthesis, structural, and biological evaluation of the arene-linked pyrazolyl methane ligands and their d9/d10 metal complexes
3) Budhai, Asheena; Omondi, Bernard; Ojwach, Stephen O.; Obuah, Collins; Osei-Twum, Emmanuel Y.; Darkwa, James; Catalysis Sci. Tech. 2013, 3(12), 3130-3135, DOI: 10.1039/c3cy00334e ; Tandem ethylene oligomerisation and Friedel-Crafts alkylation of toluene catalysed by bis-(3,5-dimethylpyrazol-1-ylmethyl)benzene nickel(ii) complexes and ethylaluminium dichloride
4) Azizzadeh, Sara; Nobakht, Valiollah; Carlucci, Lucia; Proserpio, Davide M.; Polyhedron 2017, 130, 58-66, DOI: 10.1016/j.poly.2017.03.048 ; Self-assembly of three cationic silver(I) coordination networks with flexible bis(pyrazolyl)-based linkers
5) Baladi, Elham; Nobakht, Valiollah; Tarassoli, Abbas; Proserpio, Davide M.; Carlucci, Lucia; Cryst. Growth & Des. 2018, 18(11), 7207-7218, DOI: 10.1021/acs.cgd.8b01446 ; Three Cationic, Nonporous CuI-Coordination Polymers: Structural Investigation and Vapor Iodine Capture
