Product: PCN-600(Fe)
Synonyms: NA
CAS：1630794-12-5
Basic Information
| Unit MF. | Unit MW. | ||||
| Coordination Metal | Fe | Linkers | H2TCPP (CAS:14609-54-2) | ||
| Pore Size | 3.1nm 1D Channel | Pore volume | 1.8 cm3/g | ||
| Surface Area | BET Specific surface 2200 m2/g | ||||
| Analog Structure |  |
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Product Property
| Appearance | Brick Red Crystals | |||
| Particle Size | rod-like nanoparticles | |||
Stability
1) PCN-600(Fe) is stable in air, stable in aqueous and acidic conditions(PH2-11)
2) Thermal decomposition temperature above 300 ° C
2) Thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) Lewis acid catalyst
2) Lewis acid catalyst
Characterizations
References
1) K. Wang, D. Feng, T.-F. Liu, J. Su, S. Yuan, Y.-P. Chen, M. Bosch, X. Zou and H.-C. Zhou, J. Am. Chem. Soc., 2014, 136, 13983.
2) L. Sun, J. Xie, Z. Chen, J. Wua and L. Li, Dalton Trans., 2018, 47, 9989；
3）Kecheng Wang, Dawei Feng, Tian-Fu Liu, Jie Su, Shuai Yuan, Ying-Pin Chen, Mathieu Bosch, Xiaodong Zou, Hong-Cai Zhou; Journal of the American Chemical Society, 2014, 136, 13983-13986; DOI:10.1021/ja507269n; A Series of Highly Stable Mesoporous Metalloporphyrin Fe-MOFs；
4）Zhiwei Chen, Yaoji Sun, Jiawei Wang, Xi Zhou, Xiangjian Kong, Jiashen Meng, Xingcai Zhang; ACS Nano, 2023, 17, 9003-9013; DOI: 10.1021/acsnano.2c10310; Dual-Responsive Triple-Synergistic Fe-MOF for Tumor Theranostics.;
5) Wentao Han, Xing Ma, Jingxue Wang, Fucheng Leng, Chenfan Xie, Hai-Long Jiang. J. Am. Chem. Soc., 2023, 145, 9665-9671. DOI: 10.1021/jacs.3c00957. Endowing Porphyrinic Metal-Organic Frameworks with High Stability by a Linker Desymmetrization Strategy.
