Product Name:adamantanetetrabenzoic acid
Synonymous:H4ATB;1,3,5,7-tetra(carboxyphenyl)adamantane ; Benzoic acid, 4,4',4'',4'''-tricyclo[3.3.1.13,7]decane-1,3,5,7-tetrayltetrakis-
CAS:154694-31-2
3) Zulfiqar, Sonia; Mantione, Daniele; El Tall, Omar; Sarwar, Muhammad Ilyas; Ruiperez, Fernando; Rothenberger, Alexander; Mecerreyes, David; Journal of Materials Chemistry A 2016, 4(21), 8190-8197, DOI: 10.1039/C6TA01457G ; Nanoporous amide networks based on tetraphenyladamantane for selective CO2 capture
Synonymous:H4ATB;1,3,5,7-tetra(carboxyphenyl)adamantane ; Benzoic acid, 4,4',4'',4'''-tricyclo[3.3.1.13,7]decane-1,3,5,7-tetrayltetrakis-
CAS:154694-31-2
Basic Info
M.F. | C38H32O8 | M.W. | 616.65588 | ||
Appearance | ![]() |
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:MOF-33 [r2] ; TCF-3 [r5] ; ZRTE-10 [r6]
Characterization
Reference
1) Reichert, Veronica R.; Mathias, Lon J.; Macromolecules 1994, 27(24), 7015-7023, DOI: 10.1021/ma00102a002 ; Expanded Tetrahedral Molecules from 1,3,5,7-Tetraphenyladamantane
2) Kim, Jaheon; Chen, Banglin; Reineke, Theresa M.; Li, Hailian; Eddaoudi, Mohamed; Moler, David B.; O'Keeffe, Michael; Yaghi, Omar M.; Journal of the American Chemical Society 2001, 123(34), 8239-8247, DOI: 10.1021/ja010825o ; Assembly of Metal-Organic Frameworks from Large Organic and Inorganic Secondary Building Units: New Examples and Simplifying Principles for Complex Structures4) Zhao, Tian; Heering, Christian; Boldog, Ishtvan; Domasevitch, Konstantin V.; Janiak, Christoph; CrystEngComm 2017, 19(5), 776-780, DOI: 10.1039/C6CE02384C ; A view on systematic truncation of tetrahedral ligands for coordination polymers
5) Bassanetti, Irene; Bracco, Silvia; Comotti, Angiolina; Negroni, Mattia; Bezuidenhout, Charl; Canossa, Stefano; Mazzeo, Paolo Pio; Marchio, Luciano; Sozzani, Piero; Journal of Materials Chemistry A: Materials for Energy and Sustainability 2018, 6(29), 14231-14239, DOI: 10.1039/C8TA02211A ; Flexible porous molecular materials responsive to CO2, CH4 and Xe stimuli
6) Nateghi, Bahareh; Domasevitch, Kostiantyn V.; Bulanek, Roman; Janiak, Christoph; Boldog, Ishtvan; Inorganic Chemistry 2019, 58(19), 12786-12797, DOI: 10.1021/acs.inorgchem.9b01721 ; Ligand Excess "Inverse-Defected" Zr6 Tetrahedral Tetracarboxylate Framework and Its Thermal Transformation