Product: DhaTp
Synonyms: 2,5-DhaTph ; H2P-DHPh COF ; H2P-DHPhx COF
CAS：1529776-43-9
Basic Information
| Unit MF. | C52H40N8O4 | Unit MW. | 840.94 | ||
| Linkers |
2,5-dihydroxy-1,4-Benzenedicarboxaldehyde (CAS: 1951-36-6); 5,10,15,20-Tetrakis(4-Aminophenyl)-21H,23H-Porphine (CAS: 22112-84-1) |
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| Aperture | 2 nm | Pore volume | 0.8 cm3/g | ||
| Surface Area | BET比表面>1200m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | Dark purple powders |  |
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| Particle Size | irregular clusters | |||
Stability
1) DhaTp is stable in acidic solutions for days
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
Other Features
Fluorescence:NA
Applications
1) For gas and pollutant adsorption
2) Solid pores can be used to load other catalysts
2) Solid pores can be used to load other catalysts
3) -OH groups could be used to be complxed with metals or further derivated
Characterizations
References
1）Kandambeth, Sharath; Shinde, Digambar Balaji; Panda, Manas K.; Lukose, Binit; Heine, Thomas; Banerjee, Rahul; Angewandte Chemie, International Edition 2013, 52(49), 13052-13056, DOI: 10.1002/anie.201306775 ; Enhancement of Chemical Stability and Crystallinity in Porphyrin-Containing Covalent Organic Frameworks by Intramolecular Hydrogen Bonds；
2）Xu, Hong; Chen, Xiong; Gao, Jia; Lin, Jianbin; Addicoat, Matthew; Irle, Stephan; Jiang, Donglin; Chemical Communications 2014, 50(11), 1292-1294, DOI: 10.1039/c3cc48813f ; Catalytic covalent organic frameworks via pore surface engineering；
3）Huang, Ning; Chen, Xiong; Krishna, Rajamani; Jiang, Donglin; Angewandte Chemie, International Edition 2015, 54(10), 2986-2990, DOI: 10.1002/anie.201411262 ; Two-Dimensional Covalent Organic Frameworks for Carbon Dioxide Capture through Channel-Wall Functionalization；
4) Yonghang Yang, Baokun Liang, Jakob Kreie, Mike Hambsch, Zihao Liang,Cheng Wang, Senhe Huang, Xin Dong, Li Gong, Chaolun Liang, Dongyang Lou,Zhipeng Zhou, Jiaxing Lu, Yang Yang, Xiaodong Zhuang, Haoyuan Qi, Ute Kaiser,Stefan C. B. Mannsfeld, Wei Liu, Armin Gölzhäuser & Zhikun Zheng; Nature 630, 878–883, 2024; DOI：10.1038/s41586-024-07505-x; Elastic films of single-crystal two-dimensional covalent organic frameworks
