Product Name：2,5-Di(allyloxy)terephthalic acid
Synonymous：H2(BA-BDC);1,4-Benzenedicarboxylic acid, 2,5-bis(2-propenyloxy)- ; 2,5-Bis(2-propen-1-yloxy)-1,4-benzenedicarboxylic acid; 2,5-Bis(allyloxy)-1,4-benzenedicarboxylic acid; 2,5-Bis(allyloxy)terephthalic acid
CAS：149590-60-3
3) Henke, Sebastian; Schneemann, Andreas; Wuetscher, Annika; Fischer, Roland A.; J. Am. Chem. Soc. 2012, 134(22), 9464-9474, DOI: 10.1021/ja302991b ; Directing the Breathing Behavior of Pillared-Layered Metal-Organic Frameworks via a Systematic Library of Functionalized Linkers Bearing Flexible Substituents
4) Zhang, Zhenjie; Nguyen, Ha Thi Hoang; Miller, Stephen A.; Ploskonka, Ann M.; DeCoste, Jared B.; Cohen, Seth M.; J. Am. Chem. Soc. 2016, 138(3), 920-925, DOI: 10.1021/jacs.5b11034 ; Polymer-Metal-Organic Frameworks (polyMOFs) as Water Tolerant Materials for Selective Carbon Dioxide Separations
Synonymous：H2(BA-BDC);1,4-Benzenedicarboxylic acid, 2,5-bis(2-propenyloxy)- ; 2,5-Bis(2-propen-1-yloxy)-1,4-benzenedicarboxylic acid; 2,5-Bis(allyloxy)-1,4-benzenedicarboxylic acid; 2,5-Bis(allyloxy)terephthalic acid
CAS：149590-60-3
Basic Info
| M.F. | C14H14O6 | M.W. | 278.25736 | ||
| Appearance | |||||
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis：MTV-MOF-5-H [r2]; [Zn2(2,5-BA-bdc)2(dabco)]n [r3]; [Cu2(BA-bdc)2(bpy)]n [r4]; UiO-66-BAT [r5]
Characterization
Reference
1) Steuer, Martin; Rehahn, Matthias; Ballauff, Matthias; Makromolekulare Chemie 1993, 194(8), 2395-410, Synthesis and characterization of rigid-rod polyesters bearing 3-hydroxypropyl and 3-acetoxypropyl side groups
2) Deng, Hexiang; Doonan, Christian J.; Furukawa, Hiroyasu; Ferreira, Ricardo B.; Towne, John; Knobler, Carolyn B.; Wang, Bo; Yaghi, Omar M.; Science 2010, 327(5967), 846-850, DOI: 10.1126/science.1181761 ; Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks5) Helal, Aasif; Usman, Muhammad; Arafat, Md. Eyasin; Abdelnaby, Mahmoud M.; J. Ind. Eng. Chem. 2020, 89, 104-110, DOI: 10.1016/j.jiec.2020.05.016 ; Allyl functionalized UiO-66 metal-organic framework as catalyst for synthesis of cyclic carbonates by carbon dioxide cycloaddition
