Product: TPBD-Me2
Synonyms: NA
CAS：1491156-88-7
Basic Information
| Unit MF. | C14H16N2.C9H6O6 | Unit MW. | 422.43058 | ||
| Linkers | 2,4,6-trihydroxy-1,3,5-benzenetricarbaldehyde (CAS:34374-88-4); 3,3'-Dimethylbiphenyl-4,4'-diamine (CAS: 119-93-7) | ||||
| Pore Size | 1.8 nm | Pore volume | 0.087 cm3/g | ||
| Surface Area | BET >400 m2/g | ||||
| Analog Structure |  |
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Product Property
| Appearance | Orange/Red Powders |  |
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| Particle Size | 100-200 aggregated nanoparticles | |||
Stability
1) TpBD-Me2 is stable in air for weeks, stable in aqueous and acidic conditions for more than 12hrs
2) High thermal stability, thermal decomposition temperature above 300 ° C
2) High thermal stability, thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 10 hours at 150 degree in vacuum.
Other Features
Fluorescence: NA
Applications
1) Gas (such as water vapor) and pollutant adsorption
2) With rigid framework, the TpBD-Me2 could be good carrier of catalyst. The Hydroxy group could be further derivated
2) With rigid framework, the TpBD-Me2 could be good carrier of catalyst. The Hydroxy group could be further derivated
Characterizations
References
1) Chandra, Suman; Kandambeth, Sharath; Biswal, Bishnu P.; Lukose, Binit; Kunjir, Shrikant M.; Chaudhary, Minakshi; Babarao, Ravichandar; Heine, Thomas; Banerjee, Rahul; J. Am. Chem. Soc. 2013, 135(47), 17853-17861, DOI: 10.1021/ja408121p ; Chemically Stable Multilayered Covalent Organic Nanosheets from Covalent Organic Frameworks via Mechanical Delamination
2) Karak, Suvendu; Kandambeth, Sharath; Biswal, Bishnu P.; Sasmal, Himadri Sekhar; Kumar, Sushil; Pachfule, Pradip; Banerjee, Rahul; J. Am. Chem. Soc. 2017, 139(5), 1856-1862, DOI: 10.1021/jacs.6b08815 ; Constructing Ultraporous Covalent Organic Frameworks in Seconds via an Organic Terracotta Process
3) Mellah, Abdelkarim; Fernandes, Soraia P. S.; Rodriguez, Ramon; Otero, Jose; Paz, Jairo; Cruces, Jacobo; Medina, Dana D.; Djamila, Harik; Espina, Begona; Salonen, Laura M.; Chem.- Eur. J. 2018, 24(42), 10601-10605, DOI: 10.1002/chem.201801649 ; Adsorption of Pharmaceutical Pollutants from Water Using Covalent Organic Frameworks
