Product: PCN-224(H)
Synonyms: NA
CAS：1476810-88-4
Basic Information
| Unit MF. | C144H72N12O64Zr15+2 | Unit MW. | 4362.51448 | ||
| Coordination Metal | Zr | Linkers | H2TCPP（CAS：14609-54-2） | ||
| Pore Size | 1.9nm | Pore volume | 1.59 cm3/g | ||
| Surface Area | BET Specific surface 2600 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Reddish Brown Powder |  |
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| Particle Size | ||||
Stability
1) Stable in air, stable in aqueous and acidic conditions (stable for days in PH 0-11)
2）High thermal stability, thermal decomposition temperature above 400 ° C
2）High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 12 hours at 80 degree in vacuum.
2) It is recommended to activate for 12 hours at 80 degree in vacuum.
Other Features
Fluorescence: λex=430nm, λem=652nm red light
Applications
1) Gas (such as C3H8) and pollutant adsorption(Hg2+)
2) Applied as photosensitizer in detection and photo therapy of cancer cell
2) Applied as photosensitizer in detection and photo therapy of cancer cell
3) Applied in detection of O2, NO2 and Hg2+
Characterizations
References
1) D. Feng, W.-C. Chung, Z. Wei, Z.-Y. Gu, H.-L. Jiang, Y.-P. Chen, D. J. Darensbourg, and H.-C. Zhou, J. Am. Chem. Soc. 2013, 135, 17105-17110, DOI: 10.1021/ja408084j ; Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination
2) J. Park, Q. Jiang, D. Feng, L. Mao, and H.-C. Zhou, J. Am. Chem. Soc. 2016, 138, 3518-3525, DOI: 10.1021/jacs.6b00007 ; Size-Controlled Synthesis of Porphyrinic Metal–Organic Framework and Functionalization for Targeted Photodynamic Therapy
