Product: PCN-224(H)
Synonyms: NA
CAS：1476810-88-4
Basic Information
| Unit MF. | C144H72N12O64Zr15+2 | Unit MW. | 4362.51448 | ||
| Coordination Metal | Zr | Linkers | H2TCPP（CAS：14609-54-2） | ||
| Pore Size | 1.9nm | Pore volume | 1.59 cm3/g | ||
| Surface Area | BET Specific surface 2600 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Reddish Brown Powder |  |
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| Particle Size | ||||
Stability
1) Stable in air, stable in aqueous and acidic conditions (stable for days in PH 0-11)
2）High thermal stability, thermal decomposition temperature above 400 ° C
2）High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 12 hours at 80 degree in vacuum.
2) It is recommended to activate for 12 hours at 80 degree in vacuum.
Other Features
Fluorescence: λex=430nm, λem=652nm red light
Applications
1) Gas (such as C3H8) and pollutant adsorption(Hg2+)
2) Applied as photosensitizer in detection and photo therapy of cancer cell
2) Applied as photosensitizer in detection and photo therapy of cancer cell
3) Applied in detection of O2, NO2 and Hg2+
Characterizations
References
1) D. Feng, W.-C. Chung, Z. Wei, Z.-Y. Gu, H.-L. Jiang, Y.-P. Chen, D. J. Darensbourg, and H.-C. Zhou, J. Am. Chem. Soc. 2013, 135, 17105-17110, DOI: 10.1021/ja408084j ; Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination
2) J. Park, Q. Jiang, D. Feng, L. Mao, and H.-C. Zhou, J. Am. Chem. Soc. 2016, 138, 3518-3525, DOI: 10.1021/jacs.6b00007 ; Size-Controlled Synthesis of Porphyrinic Metal–Organic Framework and Functionalization for Targeted Photodynamic Therapy;
3) Shi-Ying Li, Hong Cheng, Bo-Ru Xie, Wen-Xiu Qiu, Jing-Yue Zeng, Chu-Xin Li, Shuang-Shuang Wan, Lu Zhang, Wen-Long Liu, Xian-Zheng Zhang*;ACS Nano, 2017, 11, 7006−7018;DOI：10.1021/acsnano.7b02533;Cancer Cell Membrane Camouflaged Cascade Bioreactor for Cancer Targeted Starvation and Photodynamic Therapy;
4）Donglin Han, Yajing Han, Jun Li, Xiangmei Liu, Kelvin Wai Kwok Yeung, Yufeng Zheng, Zhenduo Cui, Xianjin Yang, Yanqin Liang, Zhaoyang Li, Shengli Zhu, Xubo Yuan, Xiaobo Feng, Cao Yang, Shuilin Wu;Applied Catalysis B: Environmental, 2020, 261, 118248;DOI：10.1016/j.apcatb.2019.118248;Enhanced photocatalytic activity and photothermal effects of cu-doped metal-organic frameworks for rapid treatment of bacteria-infected wounds；
5）Guangyao Zhai, Yuanyuan Liu, Longfei Lei, Jiajia Wang, Zeyan Wang, Zhaoke Zheng, Peng Wang, Hefeng Cheng, Ying Dai, Baibiao Huang;ACS Catalysis, 2021, 11, 1988-1994; DOI：10.1021/acscatal.0c05145; Light-Promoted CO₂ Conversion from Epoxides to Cyclic Carbonates at Ambient Conditions over a Bi-Based Metal–Organic Framework；
6）Kibeom Kim, Sungmin Lee, Eunji Jin, L. Palanikumar, Jeong Hyeon Lee, Jin Chul Kim, Jung Seung Nam, Batakrishna Jana, Tae-Hyuk Kwon, Sang Kyu Kwak, Wonyoung Choe, Ja-Hyoung Ryu;ACS Applied Materials & Interfaces, 2019, 11, 27512-27520;DOI：10.1021/acsami.9b05736;MOF × Biopolymer: Collaborative Combination of Metal−Organic Framework and Biopolymer for Advanced Anticancer Therapy；
7) Jiuhai Wang, Yadi Fan, Youhua Tan, Xin Zhao, Yu Zhang, Changming Cheng, Mo Yang;ACS Applied Materials & Interfaces, 2018, 10, 36615−36621;DOI：10.1021/acsami.8b15452;Porphyrinic Metal-organic Framework PCN224 Nanoparticles for Near-IR Induced Attenuation of Aggregation and Neurotoxicity of Alzheimer’s Amyloid-β Peptide;
