Product: UIO-66-(COOH)2
Synonyms: NA
CAS：1458048-15-1
Basic Information
| Unit MF. | C60H2O56Zr6-12.H+ | Unit MW. | 2166.97622 | ||
| Coordination Metal | Zr | Linkers | Pyromellitic acid (CAS: 89-05-4) | ||
| Pore Size | 0.8nm; 1.1nm | Pore volume | 0.5 cm3/g | ||
| Surface Area | BET Specific surface 200 m2/g, | ||||
| Analog Structure | |||||
Product Property
| Appearance | Off-White Powder |  |
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| Particle Size | 200-800nm | |||
Stability
1) UIO-66-(COOH)2 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2）High thermal stability, thermal decomposition temperature above 350 ° C
2）High thermal stability, thermal decomposition temperature above 350 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3-5 hours at 150 degree in vacuum.
2) It is recommended to activate for 3-5 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) UIO-66-(COOH)2 has branch carboxylic groups, which could be used to bind with peptide or enzyme. The carboxylic groups might also be coordinated with metal ions, used as metal probes.
2) UIO-66-(COOH)2 has branch carboxylic groups, which could be used to bind with peptide or enzyme. The carboxylic groups might also be coordinated with metal ions, used as metal probes.
Characterizations
References
1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
2) Z. Hu, Y. Peng, Z. Kang, Y. Qian, D. Zhao, Inorg. Chem. 2015, 54, 4862-4868, DOI: 10.1021/acs.inorgchem.5b00435 ; A Modulated Hydrothermal (MHT) Approach for the Facile Synthesis of UiO-66-Type MOFs；
3）Florence Ragon, Betiana Campo, Qingyuan Yang, Charlotte Martineau, Andrew D. Wiersum, Ana Lago, Vincent Guillerm, Callum Hemsley, Jarrod F. Eubank, Muthusamy Vishnuvarthan, Francis Taulelle, Patricia Horcajada, Alexandre Vimont, Philip L. Llewellyn, Marco Daturi, Sabine Devautour-Vinot, Guillaume Maurin, Christian Serre, Thomas Devic, Guillaume Clet； Journal of Materials Chemistry A, 2015, 3, 3294-3309; DOI：10.1039/c4ta03992k; Acid-functionalized UiO-66(Zr) MOFs and their evolution after intra-framework cross-linking: structural features and sorption properties；
4）Xudong Zhao, Yaxin Wang, Yali Li, Wenjuan Xue, Jian Li, Huiyuan Wu, Yuezhong Zhang, Bingzheng Li, Wen Liu, Zhuqing Gao, Hongliang Huang; Journal of Chemical & Engineering Data, 2019, 64, 2728-2735; DOI ：10.1021/acs.jced.9b00130; Synergy Effect of Pore Structure and Amount of Carboxyl Site for Effective Removal of Pb²⁺ in Metal−Organic Frameworks；
5）Fan Yang, Hongliang Huang, Xiayan Wang, Fan Li, Yuhan Gong, Chongli Zhong, Jian-Rong Li; Crystal Growth & Design, 2015, 15, 5827-5833; DOI：10.1021/acs.cgd.5b01190; Proton Conductivities in Functionalized UiO-66: Tuned Properties, Thermogravimetry-Mass and Molecular Simulation Analyses；
