Product: NU-1000
Synonyms: Zr-TBAPy
CAS：1446138-63-1
Basic Information
| Unit MF. | C88H44O32Zr6 | Unit MW. | 2160.64 | ||
| Coordination Metal | Zr | Linkers | 1,3,6,8-Tetra(4-carboxylphenyl) pyrene（CAS：933047-52-0） | ||
| Pore Size | Pore Size: 3.0 nm和1.2 nm | Pore volume | 0.466 (微孔)/1.369 (总孔) cm3/g | ||
| Surface Area | BET Specific surface >2000 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Yellow Powder |  |
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| Particle Size | 2.5um*0.5um rod crystals | |||
Stability
1) NU-1000 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-11)
2）High thermal stability, thermal decomposition temperature around 50 ° C
2）High thermal stability, thermal decomposition temperature around 50 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 12 hours at 120 degree in vacuum.
2) It is recommended to activate for 12 hours at 120 degree in vacuum.
Other Features
Fluorescence: excited at 418nm, and emitted at 518nm
Applications
1) With large pore size, NU-1000 is potential material for gas (such as carbon dioxide) and pollutant adsorption
2) With rigid framework, NU-1000 is good carrier of catalyst.
Characterizations
References
1) J. E. Mondloch, W. Bury, D. Fairen-Jimenez, S. Kwon, E. J. DeMarco, M. H. Weston, A. A. Sarjeant, S. T. Nguyen, P. C. Stair, R. Q. Snurr, O. K. Farha and J. T. Hupp, J. Am. Chem. Soc., 2013, 135, 10294-10297, DOI: 10.1021/ja4050828 ; Vapor-Phase Metalation by Atomic Layer Deposition in a Metal-Organic Framework
2) T. Islamoglu, K.-i. Otake, P. Li, C. T. Buru, A. W. Peters, I. Akpinar, S. J. Garibaya and O. K. Farha, CrystEngComm, 2018, 20, 5913-5918, DOI: 10.1039/C8CE00455B ; Revisiting the structural homogeneity of NU-1000, a Zr-based metal–organic framework
3) T. E. Webber, W.-G. Liu, S. P. Desai, C. C. Lu, D. G. Truhlar, R. L. Penn, ACS Appl. Mater. Interfaces 2017, 9, 39342– 39346, DOI: 10.1021/acsami.7b11348 ; Role of a Modulator in the Synthesis of Phase-Pure NU-1000
4) Timothy C Wang, Nicolaas A Vermeulen, In Soo Kim, Alex B F Martinson, J Fraser Stoddart,
Joseph T Hupp & Omar K Farha, Nat Protoc 2016, 11, 149–162, DOI: 10.1038/nprot.2016.001 ; Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000
