Product: SIFSIX-2-Cu-i
Synonyms: [Cu(dpa)2SiF6-i]
CAS：726124-20-5
Basic Information
| Unit MF. | C24H8N4F6SiCu | Unit MW. | 557.97 | ||
| Coordination Metal | Cu | Linkers |
1,2-bis(4-pyridyl)ethyne (CAS：73564-69-9) |
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| Pore Size | 0.5nm | Pore volume | 0.2 cm3/g | ||
| Surface Area | NA | ||||
| Analog Structure |   |
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Product Property
| Appearance | Grey Purple Powders | |||
| Particle Size | irregular bulk particles | |||
Stability
1) SIFSIX-2-Cu-i is stable in air and aqueous solution for weeks
2) Thermal decomposition temperature above 300 ° C
2) Thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate 12 hours at room temperature in vacuum
Other Features
Fluorescence:NA
Applications
1) Gas adsorption (e.g. CO2, SO2)
2) Gas Separation (ethane/ethylene)
2) Gas Separation (ethane/ethylene)
Characterizations
References
1) Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.; Cairns, Amy J.; Luebke, Ryan; Forrest, Katherine; Pham, Tony; Ma, Shengqian; Space, Brian; Wojtas, Lukasz; Eddaoudi, Mohamed; Zaworotko, Michael J.; Nature 2013), 495(7439), 80-84, DOI: 10.1038/nature11893 ; Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
2) Qian, Siheng; Xia, Ling; Yang, Lifeng; Wang, Xiaobing; Suo, Xian; Cui, Xili; Xing, Huabin From Journal of Membrane Science (2020)611, 118329, DOI: 10.1016/j.memsci.2020.118329 ; Defect-free mixed-matrix membranes consisting of anion-pillared metal-organic frameworks and poly(ionic liquid)s for separation of acetylene from ethylene；
3）Xili Cui, Kaijie Chen, Huabin Xing, Qiwei Yang, Rajamani Krishna, Zongbi Bao, Hui Wu, Wei Zhou, Xinglong Dong, Yu Han, Bin Li, Qilong Ren, Michael J. Zaworotko, Banglin Chen. Science, 2016, 353, 6295, 141-145. DOI:10.1126/science.aaf2458. Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene;
4) Yang, L. F., Cui, X. L., Yang, Q. W., Qian, S. H., Wu, H., Bao, Z. B., Zhang, Z. G., Ren, Q. L., Zhou, W., Chen, B., Xing, H. B. (2018). Advanced Materials, 30(1), 1705374. DOI: 10.1002/adma.201705374; A Single-Molecule Propyne Trap: Highly Efficient Removal of Propyne from Propylene with Anion-Pillared Ultramicroporous Materials;
5) Jieyi Zheng, Xili Cui, Qiwei Yang, Qilong Ren, Yiwen Yang, Huabin Xing; Chemical Engineering Journal, 2018, 354, 1075-1082; DOI：10.1016/j.cej.2018.08.119; Shaping of ultrahigh-loading MOF pellet with a strongly anti-tearing binder for gas separation and storage;
6）Xili Cui, Qiwei Yang, Lifeng Yang, Rajamani Krishna, Zhiguo Zhang, Zongbi Bao, Hui Wu, Qilong Ren, Wei Zhou, Banglin Chen, Huabin Xing; Advanced Materials, 2017, 29, 1606929; DOI：10.1002/adma.201606929; Ultrahigh and Selective SO₂ Uptake in Inorganic Anion-Pillared Hybrid Porous Materials;
7) Daniel O’Nolan, Amrit Kumar, Michael J. Zaworotko*; Journal of the American Chemical Society, 2017, 139, 8508-8513; DOI：10.1021/jacs.7b01682; Water Vapor Sorption in Hybrid Pillared Square Grid Materials;
8) Katherine A. Forrest, Tony Pham, Brian Space;CrystEngComm, 2017, 19, 3338-3347;DOI ：10.1039/c7ce00594f;Comparing the mechanism and energetics of CO₂ sorption in the SIFSIX series;
