Product: NH2-MIL-88B(Fe)
Synonyms: NA
CAS：1341134-09-5
Basic Information
| Unit MF. | C24H15N3O13Fe3 | Unit MW. | 720.92 | ||
| Coordination Metal | Fe | Linkers | 2-Amino Terephthalic acid (CAS:10312-55-7） | ||
| Aperture |
NA |
Pore volume | NA | ||
| Surface Area | no N2 sorption | ||||
| Analog Structure |   |
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Product Property
| Appearance | Dark Brown Powder |  |
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| Particle Size | 100*300nm fusiform cells | |||
Stability
1) NH2-MIL-88B(Fe) is stable in air and acqeous condition (PH 1-12)
2) Thermal stability, thermal decomposition temperature above 400 ° C
2) Thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence: NA
Applications
1) Gas (such as carbon dioxide) and pollutant air adsorption
2) As Fe-based Lewis acid catalyst
2) As Fe-based Lewis acid catalyst
Characterizations
References
1) C. Serre, C. Mellot-Draznieks, S. Surble, N. Audebrand, Y. Filinchuk, G. Férey, Science 2007, 315, 1828-1831, DOI: 10.1126/science.1137975 ; Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks
2) P. Sivakumar, S. Priyatharshni, K. B. Nagashanmugam, A. Thanigaivelan, K. Kumar, Mater. Res. Express 2017, 4, 085023, DOI: 10.1088/2053-1591/aa822f ; Chitosan capped nanoscale Fe-MIL-88B-NH2 metal-organic framework as drug carrier material for the pH responsive delivery of doxorubicin；
3) Shenlong Zhao, Huajie Yin, Lei Du, Liangcan He, Kun Zhao, Lin Chang, Geping Yin, Huijun Zhao, Shaoqin Liu, Zhiyong Tang. ACS Nano, 2014, 8(12): 12660-12668. DOI: 10.1021/nn505582e. Carbonized Nanoscale Metal-Organic Frameworks as High Performance Electrocatalyst for Oxygen Reduction Reaction.;
4) Xiyi Li, Yunhong Pi, Liqiong Wu, Qibin Xia, Junliang Wu, Zhong Li, Jing Xiao. Applied Catalysis B: Environmental, 2017, 202: 653-663. DOI: 10.1016/j.apcatb.2016.09.073. Facilitation of the visible light-induced Fenton-like excitation of H₂O₂ via heterojunction of g-C₃N₄/NH₂-Iron terephthalate metal-organic framework for MB degradation. ;
5) Weiqing Xu, Lei Jiao, Hongye Yan, Yu Wu, Lijuan Chen, Wenling Gu, Dan Du, Yuehe Lin, Chengzhou Zhu. ACS Applied Materials & Interfaces, 2019, 11(24): 22096-22101. DOI: 10.1021/acsami.9b03004. Glucose Oxidase-Integrated Metal−Organic Framework Hybrids as Biomimetic Cascade Nanozymes for Ultrasensitive Glucose Biosensing.;
6) Donghua Xie, Yue Ma, Yue Gu, Hongjian Zhou, Haimin Zhang, Guozhong Wang, Yunxia Zhang, Huijun Zhao. Journal of Materials Chemistry A, 2017, 5(46): 23794-23804. DOI: 10.1039/c7ta07934f. Bifunctional NH₂-MIL-88(Fe) metal–organic framework nanooctahedra for highly sensitive detection and efficient removal of arsenate in aqueous media.
7) Minh-Hao Pham, Gia-Thanh Vuong, Anh-Tuan Vu, Trong-On Do. Langmuir, 2011, 27(24): 15261-15267. DOI: 10.1021/la203570h. Novel Route to Size-Controlled FeMIL-88B(NH₂) Metal-Organic Framework Nanocrystals.
