Product: MIL-88B(Fe)
Synonyms: NA
CAS：1341134-01-7
Basic Information
| Unit MF. | C24H4O13Fe3 | Unit MW. | 667.82 | ||
| Coordination Metal | Fe | Linkers | Terephthalic acid (CAS:100-21-0） | ||
| Aperture |
with solvent 1.1-1.5nm; activated <1nm |
Pore volume | |||
| Surface Area | no N2 sorption | ||||
| Analog Structure |   |
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Product Property
| Appearance | Orange Brown Powder |  |
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| Particle Size | 300-600nm | |||
Stability
1) MIL-88B(Fe) is stable in air and acqeous condition (PH 1-12)
2）Thermal stability, thermal decomposition temperature above 400 ° C
2）Thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence: NA
Applications
1) Gas (such as carbon dioxide) and pollutant air adsorption
2) As Fe-based Lewis acid catalyst
2) As Fe-based Lewis acid catalyst
Characterizations
References
1) C. Serre, C. Mellot-Draznieks, S. Surble, N. Audebrand, Y. Filinchuk, G. Férey, Science 2007, 315, 1828-1831, DOI: 10.1126/science.1137975 Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks
2) K. Pandi, S. Prabhu, Y. Ahn, C. Park,J. Choi, Chemosphere 2020, 254,126769-126781, DOI: 10.1016/j.chemosphere.2020.126769 Design and synthesis of biopolymer-derived porous graphitic carbon covered iron-organic frameworks for depollution of arsenic from waters；
3) Cong Gao, Shuo Chen, Xie Quan, Hongtao Yu, Yaobin Zhang. Journal of Catalysis, 2017, 356, 125-132. DOI: 10.1016/j.jcat.2017.09.015. Enhanced Fenton-like catalysis by iron-based metal organic frameworks for degradation of organic pollutants.;
4) Dengke Wang, Renkun Huang, Wenjun Liu, Dengrong Sun, Zhaohui Li; ACS Catalysis, 2014, 4, 4254−4260; DOI: 10.1021/cs501169t ; Fe-Based MOFs for Photocatalytic CO2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways;
5) 5) Patricia Horcajada, Fabrice Salles, Stefan Wuttke, Thomas Devic, Daniela Heurtaux, Guillaume Maurin, Alexandre Vimont, Marco Daturi, Olivier David, Emmanuel Magnier, Norbert Stock, Yaroslav Filinchuk, Dmitry Popov, Christian Riekel, Gerard Ferey, Christian Serre. Journal of the American Chemical Society, 2011, 133(46): 17839-17847. DOI: 10.1021/ja206936e. How Linker’s Modification Controls Swelling Properties of Highly Flexible Iron(III) Dicarboxylates MIL-88. ;
6) Xianghui Li, Weilin Guo, Zhonghua Liu, Ruiqin Wang, Hua Liu；Applied Surface Science 369 2016 130–136；DOI：http://dx.doi.org/10.1016/j.apsusc.2016.02.037；Fe-based MOFs for efficient adsorption and degradation of acid orange 7 in aqueous solution via persulfate activation
7) 7) Li Shi, Tao Wang, Huabin Zhang, Kun Chang, Xianguang Meng, Huimin Liu, Jinhua Ye. Advanced Science, 2015, 2 (3). DOI: 10.1002/advs.201500006, An Amine‐Functionalized Iron (III) Metal–Organic Framework as Efficient Visible‐Light Photocatalyst for Cr (VI) Reduction.
