Product: UIO-66-SO3H
Synonyms: NA
CAS：1334722-07-4
Basic Information
| Unit MF. | C48H3O50S6Zr6-6.H+ | Unit MW. | 2120.25 | ||
| Coordination Metal | Zr | Linkers | 2-sulfoterephthalic acid (CAS: 4991-22-4) | ||
| Pore Size | 0.8nm; 1.1nm | Pore volume | NA | ||
| Surface Area | BET Specific surface 380 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | White Powder | |||
| Particle Size | NA | |||
Stability
1) UIO-66-SO3H is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2）High thermal stability, thermal decomposition temperature above 400 ° C
2）High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) Sulfo-group could be used as acidic catalyst and cation membrane
2) Sulfo-group could be used as acidic catalyst and cation membrane
Characterizations
References
1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850–13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
2) S. J. Garibaya, S. M. Cohen, Chem. Commun., 2010,46, 7700-7702, DOI: 10.1039/C0CC02990D ; Isoreticular synthesis and modification of frameworks with the UiO-66 topology;
3) Qingyuan Yang, Andrew D. Wiersum, Philip L. Llewellyn, Vincent Guillerm, Christian Serred, Guillaume Maurin; ChemComm, 2011, 47, 9603–9605; DOI ：10.1039/c1cc13543k; Functionalizing porous zirconium terephthalate UiO-66(Zr) for natural gas upgrading: a computational exploration；
4）Shyam Biswas, Jian Zhang, Zhibao Li, Ying-Ya Liu, Maciej Grzywa, Lixian Sun, Dirk Volkmer, Pascal Van Der Voort; Dalton Transactions, 2013, 42, 4730-4737; DOI：10.1039/c3dt32288b; Enhanced Selectivity of CO₂ over CH₄ in Sulphonate-, Carboxylate- and Iodo-Functionalized UiO-66 Frameworks;
5）Fan Yang, Hongliang Huang, Xiayan Wang, Fan Li, Yuhan Gong, Chongli Zhong, Jian-Rong Li; Crystal Growth & Design, 2015, 15, 5827-5833; DOI：10.1021/acs.cgd.5b01190; Proton Conductivities in Functionalized UiO-66: Tuned Properties, Thermogravimetry-Mass and Molecular Simulation Analyses；
6）Lulu Wen, Kang Sun, Xiaoshuo Liu, Weijie Yang, Luyan Li, Hai-Long Jiang*; Advanced Materials, 2023, 35, 2210669; DOI：10.1002/adma.202210669; Electronic State and Microenvironment Modulation of Metal Nanoparticles Stabilized by MOFs for Boosting Electrocatalytic Nitrogen Reduction
