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1,3,5-Tri(4-pyrazolyl)benzene

1,3,5-Tri(4-pyrazolyl)benzene

CAS NO.:1325728-09-3Formula:C15H12N6Weight: 276.295981407166
Product Name:1,​3,​5-​tris(1H-​pyrazol-​4-​yl)​benzene
Synonymous:H3BTP;1,​3,​5-​benzenetris(pyrazolate)​
CAS:1325728-09-3
Basic Info
M.F. C15H12N6 M.W. 276.29598
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:M3(BTP)​2 (M = Ni ​, Cu ​, Zn ​, Co ​) [r1] ; Fe-BTP
Characterization
HNMR
MS
FTIR
NA
HPLC
NA
Reference
1) Colombo, V.; Galli, S.; Choi, H.; Han, G.; Maspero, A.; Palmisano, G.; Masciocchi, N.; Long, J.; Chem. Sci. 2011, 2(7), 1311-1319, DOI: 10.1039/c1sc00136a ; High thermal and chemical stability in pyrazolate-bridged metal–organic frameworks with exposed metal sites 
2) Shearer, G.; Colombo, V.; Chavan, S.; Albanese, E.; Civalleri, B.; Maspero, A.; Bordiga, S.; Dal.Trans. 2013, 42(18), 6450-6458, DOI: 10.1039/c3dt32944e ; Stability vs. reactivity: understanding the adsorption properties of Ni3(BTP)2 by experimental and computational methods 
3) Vogiatzis, K.; Haldoupis, E.; Xiao, D.; Long, J.; Siepmann, J.; Gagliardi, L.; J. Phys. Chem. C 2016, 120, 33, 18707-18712, DOI: 10.1021/acs.jpcc.6b07115 ; Accelerated Computational Analysis of Metal–Organic Frameworks for Oxidation Catalysis
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