Product Name：1,1'-butadiynebenzene-3,3',5,5'-tetracarboxylic acid
Synonymous：H4BDDC ; H4BBTC ; DPBDTC;5,5'-(1,3-Butadiyne-1,4-diyl)bis[1,3-benzenedicarboxylic acid] ; 5,5'-(butadiyne-1,4-diyl)diisophthalic acid ; 1,4-diphenyl-1,3-butadiyne-3,3′′,5,5′′-tetracarboxylic acid
CAS：1239608-21-9
3) Stannard, Andrew; Russell, James C.; Blunt, Matthew O.; Salesiotis, Christos; Gimenez-Lopez, Maria del Carmen; Taleb, Nassiba; Schroeder, Martin; Champness, Neil R.; Garrahan, Juan P.; Beton, Peter H.; Nature Chem. 2012, 4(2), 112-117, DOI: 10.1038/nchem.1199 ; Broken symmetry and the variation of critical properties in the phase behaviour of supramolecular rhombus tilings
4) Rong, Jiewei; Zhang, Wenwei; Bai, Junfeng; RSC Adv. 2016, 6(105), 103714-103723, DOI: 10.1039/C6RA22001K ; Synthesis and structure of color tunable and white-light emitting lanthanide metal-organic framework materials constructed from conjugated 1,1'-butadiynebenzene-3,3',5,5'-tetracarboxylate ligand
Synonymous：H4BDDC ; H4BBTC ; DPBDTC;5,5'-(1,3-Butadiyne-1,4-diyl)bis[1,3-benzenedicarboxylic acid] ; 5,5'-(butadiyne-1,4-diyl)diisophthalic acid ; 1,4-diphenyl-1,3-butadiyne-3,3′′,5,5′′-tetracarboxylic acid
CAS：1239608-21-9
Basic Info
| M.F. | C20H10O8 | M.W. | 378.2886 | ||
| Appearance | |||||
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[Cu2(BDDC)(H2O)2]·DMF·3H2O [r1]; [Eu2(BBTC)1.5(CH3OH)2(H2O)2] [r2]; [Ln2(BBTC)1.5(DMF)4] [r4]
Characterization
Reference
1) Zheng, Bing; Liang, Zhiqiang; Li, Guanghua; Huo, Qisheng; Liu, Yunling; Cryst. Growth & Des. 2010, 10(8), 3405-3409, DOI: 10.1021/cg100046j ; Synthesis, Structure, and Gas Sorption Studies of a Three-Dimensional Metal-Organic Framework with NbO Topology
2) Wang, Li-Feng; Kang, Ling-Chen; Zhang, Wen-Wei; Wang, Fang-Ming; Ren, Xiao-Ming; Meng, Qing-Jin; Dalton Trans. 2011, 40(37), 9490-9497, DOI: 10.1039/c1dt10693g ; New europium coordination polymers with efficient energy transfer from conjugated tetracarboxylate ligands to Eu3+ ion: syntheses, structures, luminescence and magnetic properties5) Shao, Kai; Pei, Jiyan; Wang, Jia-Xin; Yang, Yu; Cui, Yuanjing; Zhou, Wei; Yildirim, Taner; Li, Bin; Chen, Banglin; Qian, Guodong; Chem. Commun. 2019, 55(76), 11402-11405, DOI: 10.1039/c9cc06239d ; Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working capacity
