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2,4,6-trimethylbenzene-1,3,5-tricarbonitrile

2,4,6-trimethylbenzene-1,3,5-tricarbonitrile

CAS NO.:1206-85-5Formula:C18H10O2Weight: 258.2708
Product Name:2,​4,​6-​Tricyanomesitylene
Synonymous:;1,​3,​5-​Benzenetricarbonitri​le, trimethyl- ​; 2,​4,​6-​Trimethyl-​1,​3,​5-​benzenetricarbonitri​le; 1,​3,​5-​Tricyano-​2,​4,​6-​trimethylbenzene
CAS:1206-85-5
Basic Info
M.F. C12H9N3 M.W. 195.21996
Appearance  
Properties
1)   It is soluble in DCM,DMF,DMSO,etc.
2)   Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis:
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Helzy, F.; Maris, T.; Wuest, J.; Cryst. Growth & Des. 2008, 8(5), 1547-1553, DOI: 10.1021/cg700798z ; Engineering Hydrogen-​Bonded Molecular Crystals Built from 1,​3,​5-​Substituted Derivatives of Benzene: 6,​6',​6''-​(1,​3,​5-​Phenylene)​tris-​1,​3,​5-​triazine-​2,​4-​diamines
2) Wang, H.; Wu, H.; Kan, J.; Chang, G.; Yao, Z.; Li, B.; Zhou, W.; Xiang, S.; Zhao, J.; Chen, B.; J. Mater. Chem. A 2017, 5(18), 8292-8296, DOI: 10.1039/C7TA01364G ; A microporous hydrogen-​bonded organic framework with amine sites for selective recognition of small molecules
3) Bi, S.; Lan, Z.; Paasch, S.; Zhang, W.; He, Y.; Zhang, C.; Liu, F.; Wu, D.; Zhuang, X.; Brunner, E.; Wang, X.; Zhang, F.; Adv. Func. Mater. 2017, 27(39), DOI: 10.1002/adfm.201703146 ; Substantial Cyano-​Substituted Fully sp2-​Carbon-​Linked Framework: Metal-​Free Approach and Visible-​Light-​Driven Hydrogen Evolution
4) Bi, S.; Thiruvengadam, P.; Wei, S.; Zhang, W.; Zhang, F.; Gao, L.; Xu, J.; Wu, D.; Chen, J.; J. Am. Chem. Soc. 2020, 142(27), 11893-11900DOI: 10.1021/jacs.0c04594 ; Vinylene-​Bridged Two-​Dimensional Covalent Organic Frameworks via Knoevenagel Condensation of Tricyanomesitylene
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