Product: MIL-100(Fe)
Synonyms: BASOLITE F300
CAS：947723-08-2 / 1195763-37-1
Basic Information
| Unit MF. | C18O15FFe3 | Unit MW. | 642.717 | ||
| Coordination Metal | Fe | Linkers | 1,3,5-Benzenetricarboxylic acid (CAS:554-95-0) | ||
| Aperture | Aperture:0.55-0.88nm; Pore Size: 2.5-2.9nm | Pore volume | 0.9 cm3/g (micropore vol. 0.55) | ||
| Surface Area | BET Specific surface 1900 m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | Orange Powder |  |
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| Particle Size | 1-10um particles or clusters | |||
Stability
1) MIL-100(Fe) is stable in air, stable in aqueous and acidic conditions(PH1-12)
2）Thermal decomposition temperature above 280 ° C
2）Thermal decomposition temperature above 280 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) Lewis acid catalyst
2) Lewis acid catalyst
Characterizations
References
1) P. Horcajada, S. Surble, C. Serre, D.-Y. Hong, Y.-K. Seo, J.-S. Chang, J.-M. Greneche, I. Margiolaki, G. Férey, Chem. Commun., 2007, 2820-2822, DOI: 10.1039/B704325B Synthesis and catalytic properties of MIL-100(Fe), an iron(iii) carboxylate with large pores;
2) You-Kyong Seo, Ji Woong Yoon, Ji Sun Lee, U-Hwang Lee, Young Kyu Hwang, Chul-Ho Jun, Patricia Horcajada, Christian Serre, Jong-San Chang. Microporous and Mesoporous Materials, 2012, 157. DOI:10.1016/j.micromeso.2012.02.027. Large scale fluorine-free synthesis of hierarchically porous iron(Ⅲ) trimesate MIL-100(Fe) with a zeolite MTN topology.；
3）Pia Küsgens , Marcus Rose , Irena Senkovska , Heidrun Fröde , Antje Henschel , Sven Siegle , Stefan Kaskel ；Volume 120, Issue 3, 15 April 2009, Pages 325-330；doi:10.1016/j.micromeso.2008.11.020；Characterization of metal-organic frameworks by water adsorption；
4）Camille Petit and Teresa J. Bandosz *；Adv. Funct. Mater. 2011, 21, 2108–2117；DOI: 10.1002/adfm.201002517. Synthesis, Characterization, and Ammonia Adsorption Properties of Mesoporous Metal–Organic Framework (MIL(Fe))–Graphite Oxide Composites: Exploring the Limits of Materials Fabrication；
5) Guesh, Kiros; Caiuby, Clarice A. D.; Mayoral, Alvaro ; Diaz-Garcia, Manuel; Diaz, Isabel; Sanchez-Sanchez, Manuel；Crystal Growth & Design 2017 , 17(4), 1806-1813；DOI：10.1021/acs.cgd.6b01776；Sustainable Preparation of MIL-100(Fe) and Its Photocatalytic Behavior in the Degradation of Methyl Orange in Water
