Product Name：4,4',4'',4'''-(9,9'-Spirobi[9H-fluorene]-2,2',7,7'-tetrayl)tetrakis[pyridine]
Synonymous：PSF ; spiro-4-py ; TPSBF;2,2',7,7'-tetra(4-pyridyl)-9,9'-spirobifluorene
CAS：1195403-94-1
3) An, Litao; Wang, Hao; Xu, Feng; Wang, Xin-Long; Wang, Fangming; Li, Jing; Inorg. Chem. 2016, 55(24), 12923-12929, DOI: 10.1021/acs.inorgchem.6b02332 ; Selective Carbon Dioxide Adsorption by Two Robust Microporous Coordination Polymers
4) Pop, Lidia; Grosu, Ioana Georgeta; Miclaus, Maria; Hadade, Niculina Daniela; Pop, Alexandra; Bende, Attila; Terec, Anamaria; Barboiu, Mihail; Grosu, Ion; Cryst. Growth Des. 2020, DOI: 10.1021/acs.cgd.0c01383 ; Halogen-Bonded Organic Frameworks of Perfluoroiodo- and Perfluorodiiodobenzene with 2,2′,7,7′-Tetrapyridyl-9,9′-spirobifluorene
Synonymous：PSF ; spiro-4-py ; TPSBF;2,2',7,7'-tetra(4-pyridyl)-9,9'-spirobifluorene
CAS：1195403-94-1
Basic Info
| M.F. | C45H28N4 | M.W. | 624.73062 | ||
| Appearance |  |
||||
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis：[Cd(pda)0.5(spiro-4-py)0.5(HCOO)]·2H2O·DMF [r1]; Halogen-Bonded Organic Frameworks (XBOF) [r4]
Characterization
Reference
1) Li, Xing; Zhang, Jie; Zhao, Yayun; Zhao, Xiuhua; Li, Feng; Li, Taohai; Li, H. L.; Chen, Liang; J. Mater. Chem. C 2015, 3(12), 6265-6270, DOI: 10.1039/C5TA00222B ; Trace amount CuII (ppm) and mixture design of CuII/PdII catalyzed Suzuki cross-coupling reactions based on the cooperative interaction of metal with a conjugated (pyridyl)spirobifluorene
2) Zhang, Jie; Li, Taohai; Zhao, Xiuhua; Zhao, Yayun; Li, Feng; Li, Xing; J. Colloid Interface Sci. 2016, 463, 13-21, DOI: 10.1016/j.jcis.2015.10.035 ; High catalytic active palladium nanoparticles gradually discharged from multilayer films to promote Suzuki, Heck and Sonogashira cross coupling reactions| 1195403-94-1-CS017842.pdf | Download |
