Product: MIL-101(Fe)
Synonyms: NA
CAS：1189182-67-9
Basic Information
| Unit MF. | C24O13ClFe3 | Unit MW. | 699.237 | ||
| Coordination Metal | Fe | Linkers | Terephthalic acid (CAS:100-21-0） | ||
| Aperture |
Aperture:1.2nm; Pore Size: 2.3-2.7nm |
Pore volume | 1.8 cm3/g | ||
| Surface Area | BET Specific surface 2800 m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | Scarlet Powder |  |
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| Particle Size | 300-600nm | |||
Stability
1) MIL-101(Fe) will decompose gradually in wet air conditions. It is also instable and will turn to other forms in polar solvent. It is suggested MIL-101(Fe) should be used within 1 week.
2）Thermal stability, thermal decomposition temperature above 300 ° C
2）Thermal stability, thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant air adsorption
2) As Fe-based Lewis acid catalyst
2) As Fe-based Lewis acid catalyst
Characterizations
References
1）D. Lupu, O. Ardelean, G. Blanita, G. Borodi, M. D. Lazar, A. R. Biris, C. Ioan, M. Mihet, I. Misan, G. Popeneciu, Int. J. Hydrogen Energy 2011, 36, 3586, DOI: 10.1016/j.ijhydene.2010.12.043
2）Wang, D.; Huang, R.; Liu, W.; Sun, D.; Li, Z. ACS Catal. 2014, 4, 4254– 4260, DOI: 10.1021/cs501169t；
3）Zhao, Meiting; Yuan, Kuo; Wang, Yun; Li, Guodong; Guo, Jun; Gu, Lin; Hu, Wenping; Zhao, Huijun; Tang, Zhiyong; Nature (2016), 538(7625), 495-499, DOI: 10.1038/nature19763 ; Metal–organic frameworks as selectivity regulators for hydrogenation reactions；
4) Dengke Wang, Renkun Huang, Wenjun Liu, Dengrong Sun, Zhaohui Li; ACS Catalysis, 2014, 4, 4254−4260; DOI: 10.1021/cs501169t ; Fe-Based MOFs for Photocatalytic CO2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways；
4) Dengke Wang, Renkun Huang, Wenjun Liu, Dengrong Sun, Zhaohui Li; ACS Catalysis, 2014, 4, 4254−4260; DOI: 10.1021/cs501169t ; Fe-Based MOFs for Photocatalytic CO2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways；
5）Dongbo Wang, Feiyue Jia, Hou Wang, Fei Chen, Ying Fang, Wenbo Dong, Guangming Zeng, Xiaoming Li, Qi Yang, Xingzhong Yuan. Journal of Colloid and Interface Science, 2018, 519, 1. DOI: 10.1016/j.jcis.2018.02.067. Simultaneously efficient adsorption and photocatalytic degradation of tetracycline by Fe-based MOFs.；
6）Feiping Zhao, Yongpeng Liu, Samia Ben Hammouda, Bhairavi Doshi, Néstor Guijarro, Xiaobo Min, Chong-Jian Tang, Mika Sillanpää, Kevin Sivula, Shaobin Wang. Applied Catalysis B: Environmental, 2020, 272, 119033. DOI: 10.1016/j.apcatb.2020.119033. MIL-101(Fe)/g-C3N4 for enhanced visible-light-driven photocatalysis toward simultaneous reduction of Cr(VI) and oxidation of bisphenol A in aqueous media.;
7）Huabin Zhang, Tao Wang, Junjie Wang, Huimin Liu, Thang Duy Dao, Mu Li, Guigao Liu, Xianguang Meng, Kun Chang, Li Shi, Tadaaki Nagao, Jinhua Ye. Advanced Materials, 2016, 28, 3703-3710. DOI: 10.1002/adma.201505187. Surface-Plasmon-Enhanced Photodriven CO₂ Reduction Catalyzed by Metal–Organic-Framework-Derived Iron Nanoparticles Encapsulated by Ultrathin Carbon Layers.
8）8）Kowsalya Vellingiri, Pawan Kumar, Akash Deep, Ki-Hyun Kim. (2017). *Chemical Engineering Journal*, 307, 1116–1126. DOI: 10.1016/j.cej.2016.09.012. Metal-organic frameworks for the adsorption of gaseous toluene under ambient temperature and pressure.
9）Qiying Xie, Yan Li, Zhaoling Lv, Hang Zhou, Xiangjun Yang, Jing Chen, Hong Guo. Scientific Reports, 2017, 7, 1. DOI:10.1038/s41598-017-03526-x. Effective Adsorption and Removal of Phosphate from Aqueous Solutions and Eutrophic Water by Fe-based MOFs of MIL-101.
10) Zongchen Li, Xuemin Liu, Wei Jin, Qingsong Hu, Yaping Zhao. (2019). Journal of Colloid and Interface Science, 554, 692–704. DOI: 10.1016/j.jcis.2019.07.046. Adsorption behavior of arsenicals on MIL-101(Fe): The role of arsenic chemical structures.
11) Han Hu, Haixuan Zhang, Ya Chen, Yujia Chen, Li Zhuang, Huase Ou. Chemical Engineering Journal, 2019, 368. DOI: 10.1016/j.cej.2019.02.190. Enhanced photocatalysis degradation of organophosphorus flame retardant using MIL-101(Fe)/persulfate: Effect of irradiation wavelength and real water matrixes.
