Product: MIL-88A(Fe)
Synonyms: NA
CAS：1138446-56-6
Basic Information
| Unit MF. | C12H6O13Fe3 | Unit MW. | 525.70 | ||
| Coordination Metal | Fe | Linkers | Fumaric acid (CAS:110-17-8） | ||
| Aperture |
with solvent 1.1-1.4nm; activated <1nm |
Pore volume | |||
| Surface Area | no N2 sorption | ||||
| Analog Structure |   |
||||
Product Property
| Appearance | Orange Brown Powder |  |
||
| Particle Size | 300nm*2um | |||
Stability
1) MIL-88A(Fe) is stable in air and acidic solutions
2）Thermal stability, thermal decomposition temperature above 250 ° C
2）Thermal stability, thermal decomposition temperature above 250 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence: NA
Applications
1) Gas (such as carbon dioxide) and pollutant air adsorption
2) As Fe-based Lewis acid catalyst
2) As Fe-based Lewis acid catalyst
Characterizations
References
1) C. Serre, C. Mellot-Draznieks, S. Surble, N. Audebrand, Y. Filinchuk, G. Ferey. Science 2007, 315 (5820) , 1828-1831, DOI: 10.1126/science.1137975 ; Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks.
2）L. Wang, Y. Zhang, X. Li, Y. Xie, J. He, J. Yu, Y. Song, Sci Rep 2015, 5, 14341, DOI: 10.1038/srep14341 ; The MIL-88A-Derived Fe3O4-Carbon Hierarchical Nanocomposites for Electrochemical Sensing；
3）Ying Zhang, Jiabin Zhou, Xin Chen, Luo Wang, Weiquan Cai. Chemical Engineering Journal, 2019, DOI: 10.1016/j.cej.2019.03.108. Coupling of heterogeneous advanced oxidation processes and photocatalysis in efficient degradation of tetracycline hydrochloride by Fe-based MOFs: synergistic effect and degradation pathway.；
4）Ning Liu, Wenyuan Huang, Xiaodong Zhang, Liang Tang, Liang Wang, Yuxin Wang, Minghong Wu. Applied Catalysis B: Environmental, 2017; DOI: 10.1016/j.apcatb.2017.09.020. Ultrathin graphene oxide encapsulated in uniform MIL-88A(Fe) for enhanced visible light-driven photodegradation of RhB.;
5) Xiao-Hong Yi, Haodong Ji, Chong-Chen Wang, Yang Li, Yu-Hang Li, Chen Zhao, Ao Wang, Huifen Fu, Peng Wang, Xu Zhao, Wen Liu. Applied Catalysis B: Environmental, 2021; DOI: 10.1016/j.apcatb.2021.120229. Photocatalysis-activated SR-AOP over PDINH/MIL-88A(Fe) composites for boosted chloroquine phosphate degradation: performance, mechanism, pathway and DFT calculations.;
6) T. Chalati, P. Horcajada, R. Gref, P. Couvreur, C. Serre; Journal of Materials Chemistry, 2011, 21, 2220-2227; DOI: 10.1039/c0jm03563g; Optimisation of the synthesis of MOF nanoparticles made of flexible porous iron fumarate MIL-88A.;
7) Wen-Tao Xu, Lin Ma, Fei Ke, Fu-Min Peng, Geng-Sheng Xu, Yu-Hua Shen, Jun-Fa Zhu, Ling-Guang Qiu, Yu-Peng Yuan*; Dalton Transactions, 2014, 43, 3792-3798; DOI: 10.1039/c3dt52574k; Metal–organic frameworks MIL-88A hexagonal microrods as a new photocatalyst for efficient decolorization of methylene blue dye.
