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ZIF-90

ZIF-90

CAS NO.:1062147-37-8Formula:C8H8N4O2.ZnWeight: 257.56

Product: ZIF-90
Synonyms: NA
CAS:1062147-37-8

Basic Information
Unit MF. C4H4N2O.Zn Unit MW. 161.48
Coordination  Metal Zn Linkers Imidazole-2-Carboxaldehyde (CAS:10111-08-7)
Pore Size Aperture 0.35nm; Pore size 1.1nm Pore volume Micropore 0.4 cm3/g
Surface Area BET Specific surface 1500 m2/g,
Analog Structure     
Product Property
Appearance Grey/Off-white Powder  
Particle Size 100nm (For bioresearch)
Stability
1) ZIF-90 is stable in air, stable in aqueous and alkaline conditions, instable in acidic condition
2) Thermal decomposition temperature around 300 ° C
Preservation
1) Keep in dry and cool conditoin
2) It is recommended to activate for 2 hours at 100 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas and pollutant adsorption
2) Good drug carrier, which could be decomposed in stomach and release the drug content
Characterizations
XRD
BET
BET-ZIF-90 s
SEM
SEM-ZIF-90-100nm
FTIR
FTIR-ZIF-90
References
1)W. Morris, C. J. Doonan, H. Furukawa, R. Banerjee, O. M. Yaghi, J. Am. Chem. Soc. 2008, 130, 38, 12626-12627, DOI: 10.1021/ja805222x Crystals as Molecules: Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks
2) H. Jin, Y. Li, X. Liu, Y. Ban, Y. Peng, W. Jiao, W. Yang, Chem. Eng. Sci. 2015, 124, 170–178, DOI: 10.1016/j.ces.2014.07.017 ; Recovery of HMF from aqueous solution by zeolitic imidazolate frameworks