Product Name：Hexakis(trimethylsilylethynyl)benzene
Synonymous：HTEB ; Silane, (1,2,3,4,5,6-benzenehexaylhexa-2,1-ethynediyl)hexakis[trimethyl- ; 1,2,3,4,5,6-Hexakis[2-(trimethylsilyl)ethynyl]benzene
CAS：100516-62-9
Synonymous：HTEB ; Silane, (1,2,3,4,5,6-benzenehexaylhexa-2,1-ethynediyl)hexakis[trimethyl- ; 1,2,3,4,5,6-Hexakis[2-(trimethylsilyl)ethynyl]benzene
CAS：100516-62-9
Basic Info
| M.F. | C36H54Si6 | M.W. | 655.32696 | ||
| Appearance |  |
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Properties
1) It is soluble in DCM, DMF, DMSO, etc.
2) 2-8 ℃ sealed storage
2) 2-8 ℃ sealed storage
Appications
1) It could be used as monomer linkers for synthesis of Graphyne or Graphdiyne [r4, r5]
2) As precursors for phenylenes [r3]
Characterization
Reference
1) Diercks, Rainer; Armstrong, James C.; Boese, Roland; Vollhardt, K. Peter C.; Angew. Chem. 1986, 98(3), 270-271, Hexaethynylbenzene
2) Neenan, Thomas X.; Whitesides, George M.; J. Org. Chem. 1988, 53(11), 2489-2496, DOI: 10.1021/jo00246a018 ; Synthesis of high carbon materials from acetylenic precursors. Preparation of aromatic monomers bearing multiple ethynyl groups
3) Holmes, Daniel; Kumaraswamy, Sriram; Matzger, Adam J.; Vollhardt, K. Peter C.; Chem.-Eur. J. 1999, 5(11), 3399-3412, DOI: 10.1002/(SICI)1521-3765(19991105)5:11<3399::AID-CHEM3399>3.0.CO;2-V ; On the nature of nonplanarity in the [N]phenylenes
4) Huang, Changshui; Zhang, Shengliang; Liu, Huibiao; Li, Yongjun; Cui, Guanglei; Li, Yuliang; Nano Energy 2015, 11, 481-489, DOI: 10.1016/j.nanoen.2014.11.036 ; Graphdiyne for high capacity and long-life lithium storage
5) Zhou, Jingyuan; Gao, Xin; Liu, Rong; Xie, Ziqian; Yang, Jin; Zhang, Shuqing; Zhang, Gengmin; Liu, Huibiao; Li, Yuliang; Zhang, Jin; Liu, Zhongfan; J. Am. Chem. Soc. 2015, 137(24), 7596-7599, DOI: 10.1021/jacs.5b04057 ; Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction
